ArticleAngewandte Chemie (International ed. in English)2021
Chemoselective γ-Oxidation of β,γ-Unsaturated Amides with TEMPO.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- In Search of Radical Transformations from Metal Enolates. Direct Reactions ofThe Journal of organic chemistry · 2025Article
- Regioselective Synthesis of β,γ-Unsaturated Amides from Unactivated Alkenes.The Journal of organic chemistry · 2025Article
- New Strategies for the Functionalization of Carbonyl Derivatives via α-Umpolung: From Enolates to Enolonium Ions.Accounts of chemical research · 2023Article
- Molecular flavin catalysts for C-H functionalisation and derivatisation of dehydroamino acids.Chemical science · 2022Article
- Challenges and Breakthroughs in Selective Amide Activation.Angewandte Chemie (International ed. in English) · 2022Review
- Challenges and Breakthroughs in Selective Amide Activation.Angewandte Chemie (Weinheim an der Bergstrasse, Germany) · 2022Review
- Multicatalysis protocol enables direct and versatile enantioselective reductive transformations of secondary amides.Science advances · 2022Article
- Chemoselective γ-Oxidation of β,γ-Unsaturated Amides with TEMPO.Angewandte Chemie (International ed. in English) · 2021Article
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Authors and funding
6 authors.
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Abstract
A chemoselective and robust protocol for the γ-oxidation of β,γ-unsaturated amides is reported. In this method, electrophilic amide activation, in a rare application to unsaturated amides, enables a regioselective reaction with TEMPO resulting in the title products. Radical cyclisation reactions and oxidation of the synthesised products highlight the synthetic utility of the products obtained.
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Registered trials
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