ArticleNature communications2021
Catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides via selective C-F bond activation.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
14 citing papers in PubMed.
- Upcycling of PTFE and PVDF to fluorochemicals through mechanochemical process.Nature communications · 2025Article
- Single Photocatalytic Hydrosilylation of Alkenes for the Synthesis of Bis(silyl) and Silaboryl Alkanes.JACS Au · 2025Article
- Recent advances and perspectives in synthetic applications of silylboronates as silyl radical precursors.Chemical science · 2025Review
- Electrophilic aromatic substitution using fluorinated isoxazolines at the C5 positionRSC advances · 2024Article
- The role of silicon in drug discovery: a review.RSC medicinal chemistry · 2024Review
- Nickel/photoredox-catalyzed three-component silylacylation of acrylatesChemical science · 2024Article
- Cross-coupling of organic fluorides with allenes: a silyl-radical-relay pathway for the construction of α-alkynyl-substituted all-carbon quaternary centres.Chemical science · 2024Article
- Ligand-modulated nickel-catalyzed regioselective silylalkylation of alkenes.Nature communications · 2023Article
- Base-mediated C-B bond activation of benzylic boronate for the rapid construction of β-silyl/boryl functionalized 1,1-diarylalkanes from aromatic alkenes.Chemical science · 2023Article
- Synthesis of triarylmethanes by silyl radical-mediated cross-coupling of aryl fluorides and arylmethanes.Chemical science · 2023Article
- Transition-metal-free silylboronate-mediated cross-couplings of organic fluorides with amines.Nature communications · 2023Article
- Regioselective Ni-Catalyzed reductive alkylsilylation of acrylonitrile with unactivated alkyl bromides and chlorosilanes.Nature communications · 2022Article
- Intermolecular Carbosilylation of α-Olefins with C(spAngewandte Chemie (International ed. in English) · 2022Article
- Silylboronate-Mediated Defluorosilylation of Aryl Fluorides with or without Ni-Catalyst.Frontiers in chemistry · 2021Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
A regioselective carbosilylation of alkenes has emerged as a powerful strategy to access molecules with functionalized silylated alkanes, by incorporating silyl and carbon groups across an alkene double bond. However, to the best of our knowledge, organic fluorides have never been used in this protocol. Here we disclose the catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides mediated by
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.