ReviewChemical reviews2021
Carbonyl-Olefin Metathesis.
Review in Chemical reviews, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 37 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
37 citing papers in PubMed, 144 citations in OpenAlex.
- Article
- Transition Metal-Free Borata-Alkene/Alkyne Metathesis Enables Access to Cyclopentenes.Angewandte Chemie (International ed. in English) · 2026Article
- Photo-Stitching of Nitroalkanes via Cross-Denitrative Olefination.Journal of the American Chemical Society · 2026Article
- Diastereoselective Synthesis of Axially Chiral Skipped Ene-Allenes Containing a Quaternary Stereocenter by Cyclopropene-Allene Metathesis.Angewandte Chemie (International ed. in English) · 2026Article
- Olefination of Alcohols and Alkyl Halides via Oxidative Alkyl Electrophile-Olefin Metathesis.Organic letters · 2026Article
- Hydrazine-mediated carbonyl-alkyne/allene reductive olefination.Nature communications · 2026Article
- Epoxide apparent exchange reaction for the precise synthesis of epoxy resins.Nature communications · 2026Article
- Phenanthrene-like Benzodichalcogenophenes: Synthesis, Electrochemical Behavior and Applications.Molecules (Basel, Switzerland) · 2026Review
- A Potassium Base-Promoted Intramolecular Enolate-Olefin Metathesis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Carbonyl-Olefin/Alkyne Metathesis Reactions Catalyzed by Bifunctional H-USY Zeolites.Journal of the American Chemical Society · 2025Article
- CaChemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Redox-neutral photocatalytic hydrodealkenylation of aryl olefins.Nature communications · 2025Article
- Mechanistic Investigations into the Olefination of Oximes and Hydrazones Support Intermediate Ruthenium Nitrides.Journal of the American Chemical Society · 2025Article
- Oxetane Cleavage Pathways in the Excited State: Photochemical Kinetic Resolution as an Approach to Enantiopure Oxetanes.Journal of the American Chemical Society · 2025Article
- Theoretical Investigations of Substrate Behavior in FeClACS omega · 2025Article
- Alkene Diversification through a Molecular Recasting Strategy Enabled byResearch (Washington, D.C.) · 2025Article
- Triazenolysis of alkenes as an aza version of ozonolysis.Nature chemistry · 2025Article
- Catalytic Aldehyde-Alkyne Couplings Triggered by Ketyl Radicals.Organic letters · 2024Article
- Cyclization Strategies in Carbonyl-Olefin Metathesis: An Up-to-Date Review.Molecules (Basel, Switzerland) · 2024Review
- α-Carbonyl Rh-Carbenoid Initiated Cascade Assembly of Diazobarbiturates with Alkylidene Pyrazolones for Synthesis of Spirofuropyrimidines.Molecules (Basel, Switzerland) · 2024Article
Corrections and comments
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Authors and funding
7 authors at 2 institutions in 1 country.
Funding
Abstract
This Review describes the development of strategies for carbonyl-olefin metathesis reactions relying on stepwise, stoichiometric, or catalytic approaches. A comprehensive overview of currently available methods is provided starting with Paternò-Büchi cycloadditions between carbonyls and alkenes, followed by fragmentation of the resulting oxetanes, metal alkylidene-mediated strategies, [3 + 2]-cycloaddition approaches with strained hydrazines as organocatalysts, Lewis acid-mediated and Lewis acid-catalyzed strategies relying on the formation of intermediate oxetanes, and protocols based on initial carbon-carbon bond formation between carbonyls and alkenes and subsequent Grob-fragmentations. The Review concludes with an overview of applications of these currently available methods for carbonyl-olefin metathesis in complex molecule synthesis. Over the past eight years, the field of carbonyl-olefin metathesis has grown significantly and expanded from stoichiometric reaction protocols to efficient catalytic strategies for ring-closing, ring-opening, and cross carbonyl-olefin metathesis. The aim of this Review is to capture the status quo of the field and is expected to contribute to further advancements in carbonyl-olefin metathesis in the coming years.
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What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.