Evidence map›Paper›PMID 34127660›Full record

ArticleNature communications2021

Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La

Shunsuke Sasaki, Maria Teresa Caldes, Catherine Guillot-Deudon, Isabelle Braems, Gwladys Steciuk, Lukáš Palatinus, Eric Gautron, Gilles Frapper, Etienne Janod, Benoît Corraze and 2 more

Abstract read
In one paragraph

Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
  4. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Shunsuke SasakiUniversité de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMN, Nantes, F-44000, France.
Maria Teresa CaldesUniversité de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMN, Nantes, F-44000, France.
Catherine Guillot-DeudonUniversité de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMN, Nantes, F-44000, France.
Isabelle BraemsUniversité de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMN, Nantes, F-44000, France.
Gwladys SteciukInstitute of Physics ASCR, v.v.i., Na Slovance 1999/2, Praha 8, 18221, Czechia.
Lukáš PalatinusInstitute of Physics ASCR, v.v.i., Na Slovance 1999/2, Praha 8, 18221, Czechia.ORCID http://orcid.org/0000-0002-8987-8164
Eric GautronUniversité de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMN, Nantes, F-44000, France.
Gilles FrapperInstitut de Chimie des Milieux et Matériaux de Poitiers, 4 rue Michel Brunet, Poitiers cedex 09, 86073, France.ORCID http://orcid.org/0000-0001-5177-6691
Etienne JanodUniversité de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMN, Nantes, F-44000, France.ORCID http://orcid.org/0000-0002-2430-9542
Benoît CorrazeUniversité de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMN, Nantes, F-44000, France.
Stéphane JobicUniversité de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMN, Nantes, F-44000, France. Stephane.Jobic@cnrs-imn.fr.ORCID http://orcid.org/0000-0002-1900-0030
Laurent CarioUniversité de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMN, Nantes, F-44000, France. Laurent.Cario@cnrs-imn.fr.ORCID http://orcid.org/0000-0001-5720-4395

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Designing and synthesising new metastable compounds is a major challenge of today's material science. While exploration of metastable oxides has seen decades-long advancement thanks to the topochemical deintercalation of oxygen as recently spotlighted with the discovery of nickelate superconductor, such unique synthetic pathway has not yet been found for chalcogenide compounds. Here we combine an original soft chemistry approach, structure prediction calculations and advanced electron microscopy techniques to demonstrate the topochemical deintercalation/reintercalation of sulfur in a layered oxychalcogenide leading to the design of novel metastable phases. We demonstrate that La

Identifiers

PMID34127660
PMCPMC8203606

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.