Evidence map›Paper›PMID 34123300›Full record

ArticleChemical science2020

Enantioselective oxygenation of exocyclic methylene groups by a manganese porphyrin catalyst with a chiral recognition site.

Finn Burg, Stefan Breitenlechner, Christian Jandl, Thorsten Bach

Abstract read
In one paragraph

Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.

0numbers the graph read from it
0cells of the map it votes in
12citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

12 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Synthesis of 2-Oxoquinoline Derivatives as Dual Pim and mTORC Protein Kinase Inhibitors.Medicinal chemistry research : an international journal for rapid communications on design and mechanisms of action of biologically active agents · 2022
    Article
  6. Article
  7. Article
  8. Article
  9. Catalytic enantioselective C(spNature communications · 2021
    Review
  10. Review
  11. Review
  12. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Finn BurgDepartment Chemie, Catalysis Research Center (CRC), Technische Universität München 85747 Garching Germany thorsten.bach@ch.tum.de +49 89 28913315 +49 89 28913330.ORCID https://orcid.org/0000-0002-8038-5638
Stefan BreitenlechnerDepartment Chemie, Catalysis Research Center (CRC), Technische Universität München 85747 Garching Germany thorsten.bach@ch.tum.de +49 89 28913315 +49 89 28913330.ORCID https://orcid.org/0000-0001-5519-1922
Christian JandlDepartment Chemie, Catalysis Research Center (CRC), Technische Universität München 85747 Garching Germany thorsten.bach@ch.tum.de +49 89 28913315 +49 89 28913330.
Thorsten BachDepartment Chemie, Catalysis Research Center (CRC), Technische Universität München 85747 Garching Germany thorsten.bach@ch.tum.de +49 89 28913315 +49 89 28913330.ORCID https://orcid.org/0000-0002-1342-0202

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The natural enzyme cytochrome P450 is widely recognised for its unique ability to catalyse highly selective oxygen insertion reactions into unactivated C-H bonds under mild conditions. Its exceptional potential for organic synthesis served as an inspiration for the presented biomimetic hydroxylation approach.

Identifiers

PMID34123300
PMCPMC8150113

What OpenQuestion holds

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LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.