ArticleChemical science2019
Switchable electrical conductivity in a three-dimensional metal-organic framework
Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
9 citing papers in PubMed, 71 citations in OpenAlex.
- Insights and opportunities from materials chemistry research at primarily undergraduate institutions in the U.S.Communications chemistry · 2026Review
- Optical Phenomena in Molecule-Based Magnetic Materials.Chemical reviews · 2024Review
- Strategies to Improve Electrical Conductivity in Metal-Organic Frameworks: A Comparative Study.Crystal growth & design · 2024Review
- Ligand field tuning of d-orbital energies in metal-organic framework clusters.Communications chemistry · 2023Article
- An electrically conductive metallocycle: densely packed molecular hexagons with π-stacked radicals.Chemical science · 2022Article
- A switchable sensor and scavenger: detection and removal of fluorinated chemical species by a luminescent metal-organic framework.Chemical science · 2021Article
- Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks.Chemical science · 2021Article
- Strategies for Controlling Through-Space Charge Transport in Metal-Organic Frameworks via Structural Modifications.Nanomaterials (Basel, Switzerland) · 2020Article
- Electrically Conductive 3D Metal-Organic Framework Featuring π-Acidic Hexaazatriphenylene Hexacarbonitrile Ligands with Anion-π Interaction and Efficient Charge-Transport Capabilities.ACS applied materials & interfaces · 2020Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
8 authors at 4 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Redox-active metal-organic frameworks (MOFs) are promising materials for a number of next-generation technologies, and recent work has shown that redox manipulation can dramatically enhance electrical conductivity in MOFs. However, ligand-based strategies for controlling conductivity remain under-developed, particularly those that make use of reversible redox processes. Here we report the first use of ligand n-doping to engender electrical conductivity in a porous 3D MOF, leading to tunable conductivity values that span over six orders of magnitude. Moreover, this work represents the first example of redox switching leading to reversible conductivity changes in a 3D MOF.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.