ArticleChemical science2020
Effects of ligands on the migratory insertion of alkenes into rhodium-oxygen bonds.
Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
4 citing papers in PubMed.
- Mechanistic Insights Into the Transition-Metal-Catalyzed Dual Reactivity Mode of Vinyl Ethylene Carbonates With Anilines.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Cobalt-catalyzed radical-mediated carbon-carbon scissionChemical science · 2023Article
- Rhodium(III)-Catalyzed Anti-Markovnikov Hydroamidation of Unactivated Alkenes Using Dioxazolones as Amidating Reagents.Journal of the American Chemical Society · 2022Article
- A comprehensive understanding of carbon-carbon bond formation by alkyne migratory insertion into manganacycles.Chemical science · 2022Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Migratory insertions of olefins into metal-oxygen bonds are elementary steps of important catalytic processes, but well characterised complexes that undergo this reaction are rare, and little information on the effects of ancillary ligands on such reactions has been gained. We report a series of alkoxo alkene complexes of rhodium(i) that contain a range of bidentate ligands and that undergo insertion of the alkene. Our results show that complexes containing less electron-donating ancillary ligands react faster than their counterparts containing more electron-donating ancillary ligands, and that complexes possessing ligands with larger bite angles react faster than those with smaller bite angles. External added ligands had several effects on the reactions, including an inhibition of olefin isomerisation in the product and acceleration of the displacement of the product from complexes of ancillary ligands with small bite angles. Complementary computational studies help elucidate the details of these insertion processes.
Identifiers
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Registered trials
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