Evidence map›Paper›PMID 34123171›Full record

ArticleChemical science2020

Size-selective Pt siderophores based on redox active azo-aromatic ligands.

Debabrata Sengupta, Sreetosh Goswami, Rajdeep Banerjee, Matthew J Guberman-Pfeffer, Abhijeet Patra, Anirban Dutta, Rajib Pramanick, Shobhana Narasimhan, Narayan Pradhan, Victor Batista and 2 more

Abstract read
In one paragraph

Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Debabrata SenguptaSchool of Chemical Sciences, Indian Association for the Cultivation of Science Jadavpur Kolkata 700032 India icsg@iacs.res.in.ORCID https://orcid.org/0000-0001-7212-3761
Sreetosh GoswamiNUSNNI-NanoCore, National University of Singapore Singapore 117411 Singapore sreetosh@u.nus.edu.ORCID https://orcid.org/0000-0002-1143-0693
Rajdeep BanerjeeTheoretical Sciences Unit, School of Advanced Materials, Jawaharlal Nehru Centre for Advanced Scientific Research Jakkur Bangalore 560064 India shobhana@jncsir.ac.in.
Matthew J Guberman-PfefferDepartment of Chemistry, Yale University 225 Prospect Street New Haven Connecticut 06520 USA victor.batista@yale.edu.
Abhijeet PatraNUSNNI-NanoCore, National University of Singapore Singapore 117411 Singapore sreetosh@u.nus.edu.
Anirban DuttaSchool of Materials Sciences, Indian Association for the Cultivation of Science Jadavpur Kolkata 700032 India camnp@iacs.res.in.
Rajib PramanickSchool of Chemical Sciences, Indian Association for the Cultivation of Science Jadavpur Kolkata 700032 India icsg@iacs.res.in.ORCID https://orcid.org/0000-0001-8876-7238
Shobhana NarasimhanTheoretical Sciences Unit, School of Advanced Materials, Jawaharlal Nehru Centre for Advanced Scientific Research Jakkur Bangalore 560064 India shobhana@jncsir.ac.in.
Narayan PradhanSchool of Materials Sciences, Indian Association for the Cultivation of Science Jadavpur Kolkata 700032 India camnp@iacs.res.in.
Victor BatistaDepartment of Chemistry, Yale University 225 Prospect Street New Haven Connecticut 06520 USA victor.batista@yale.edu.
T VenkatesanNUSNNI-NanoCore, National University of Singapore Singapore 117411 Singapore sreetosh@u.nus.edu.
Sreebrata GoswamiSchool of Chemical Sciences, Indian Association for the Cultivation of Science Jadavpur Kolkata 700032 India icsg@iacs.res.in.ORCID https://orcid.org/0000-0002-4380-5656

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We demonstrate a strategy inspired by natural siderophores for the dissolution of platinum nanoparticles that could enable their size-selective synthesis, toxicological assessment, and the recycling of this precious metal. From the fabrication of electronics to biomedical diagnosis and therapy, PtNPs find increasing use. Mitigating concerns over potential human toxicity and the need to recover precious metal from industrial debris motivates the study of bio-friendly reagents to replace traditional harsh etchants. Herein, we report a family of redox-active siderophore-viz. π-acceptor azo aromatic ligands (L) that spontaneously ionize and chelate Pt atoms selectively from nanoparticles of size ≤6 nm. The reaction produces a monometallic diradical complex, Pt

Identifiers

PMID34123171
PMCPMC8163438

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.