ArticleChemical science2020
Stability of radical-functionalized gold surfaces by self-assembly and on-surface chemistry.
Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Probing Radical-Induced Magnetic Moment Modulation at Cobalt Interfaces via Soft X-Ray Photoelectron Spectroscopy.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Electronically Perturbed Vibrational Excitations of the Luminescing Stable Blatter Radical.ACS nano · 2025Article
- Long-Term Degradation Mechanisms in Application-Implemented Radical Thin Films.ACS applied materials & interfaces · 2023Article
- Thermally UltrarobustJournal of the American Chemical Society · 2023Article
- High-Spin (Journal of the American Chemical Society · 2022Article
- Tethered Blatter Radical for Molecular Grafting: Synthesis of 6-Hydroxyhexyloxy, Hydroxymethyl, and Bis(hydroxymethyl) Derivatives and Their Functionalization.Molecules (Basel, Switzerland) · 2022Article
- Synthesis and Thin Films of Thermally Robust Quartet (Journal of the American Chemical Society · 2021Article
Corrections and comments
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Authors and funding
11 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We have investigated the radical functionalization of gold surfaces with a derivative of the perchlorotriphenylmethyl (PTM) radical using two methods: by chemisorption from the radical solution and by on-surface chemical derivation from a precursor. We have investigated the obtained self-assembled monolayers by photon-energy dependent X-ray photoelectron spectroscopy. Our results show that the molecules were successfully anchored on the surfaces. We have used a robust method that can be applied to a variety of materials to assess the stability of the functionalized interface. The monolayers are characterized by air and X-ray beam stability unprecedented for films of organic radicals. Over very long X-ray beam exposure we observed a dynamic nature of the radical-Au complex. The results clearly indicate that (mono)layers of PTM radical derivatives have the necessary stability to withstand device applications.
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Registered trials
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