ArticleChemical science2020
Selective α,δ-hydrocarboxylation of conjugated dienes utilizing CO
Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed, 91 citations in OpenAlex.
- High-Pressure Electrosynthesis of Succinic and Adipic Acids From COChemSusChem · 2026Article
- Electrochemical deutero-(di)carboxylations for the preparation of deuterium-labeled medicinal building blocks.Nature communications · 2025Article
- Vinylogous Electrochemical Carboxylation of Dienones.ACS electrochemistry · 2025Article
- Catalytic transformation of carbon dioxide into seven-membered heterocycles and their domino transformation into bicyclic oxazolidinones.Nature communications · 2025Article
- Nickel-Catalyzed Hydrocarboxylation of Terminal Unactivated Alkenes: Formation of Branched Carboxylic Acids and Competing Catalyst Deactivation from COOrganometallics · 2024Article
- Straightforward synthesis of functionalized γ-Lactams using impure CONature communications · 2023Article
- Electrochemical Late-Stage Functionalization.Chemical reviews · 2023Review
- Ketone-Olefin Coupling of Aliphatic and Aromatic Carbonyls Catalyzed by Excited-State Acridine Radicals.Journal of the American Chemical Society · 2022Article
- Electrocatalysis with Molecular Transition-Metal Complexes for Reductive Organic Synthesis.JACS Au · 2022Review
- Recent Advances in C(spACS organic & inorganic Au · 2022Review
- Nickel-catalyzed electrochemical carboxylation of unactivated aryl and alkyl halides with CONature communications · 2021Article
- Electrocatalytic Reactions for Converting COSmall science · 2021Article
- Suppressing carboxylate nucleophilicity with inorganic salts enables selective electrocarboxylation without sacrificial anodes.Chemical science · 2021Article
- Selective Electrosynthetic Hydrocarboxylation of α,β-Unsaturated Esters with Carbon Dioxide*.Angewandte Chemie (International ed. in English) · 2021Article
- Electrochemical Dehydrogenative C(spChemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Direct electrochemical defluorinative carboxylation of α-CFChemical science · 2020Article
Corrections and comments
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Authors and funding
6 authors at 3 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
To date the majority of diene carboxylation processes afford the α,δ-dicarboxylated product, the selective mono-carboxylation of dienes is a significant challenge and the major product reported under transition metal catalysis arises from carboxylation at the α-carbon. Herein we report a new electrosynthetic approach, that does not rely on a sacrificial electrode, the reported method allows unprecedented direct access to carboxylic acids derived from dienes at the δ-position. In addition, the α,δ-dicarboxylic acid or the α,δ-reduced alkene can be easily accessed by simple modification of the reaction conditions.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.