ArticleChemical science2020
Catalytic three-component C-C bond forming dearomatization of bromoarenes with malonates and diazo compounds.
Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Arene activation via π-bond localization: concepts and opportunities.Beilstein journal of organic chemistry · 2026Review
- Copper-Catalyzed DearomativeACS catalysis · 2024Article
- Radical-Dearomative Generation of Cyclohexadienyl Pd(II) toward the 3D Transformation of Nonactivated Phenyl Rings.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Asymmetric dearomative cyclopropanation of naphthalenes to construct polycyclic compounds.Chemical science · 2022Article
- Rhodium-Catalyzed C-H Methylation and Alkylation Reactions by Carbene-Transfer Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Pd-catalyzed allylative dearomatisation using Grignard reagents.Chemical communications (Cambridge, England) · 2021Article
- Multicomponent Reactions Involving Diazo Reagents: A 5-Year Update.Molecules (Basel, Switzerland) · 2021Review
- Metal-free tandem carbene N-H insertions and C-C bond cleavages.Chemical science · 2020Article
- Catalytic three-component C-C bond forming dearomatization of bromoarenes with malonates and diazo compounds.Chemical science · 2020Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A Pd-catalyzed dearomative three-component C-C bond formation of bromoarenes with diazo compounds and malonates was developed. Various bromoarenes ranging from benzenoids to azines and heteroles were transformed to the corresponding substituted alicyclic molecules. The key to this reaction is the generation of a benzyl-palladium intermediate, which reacts with malonates to form a Pd-
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Registered trials
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