ArticleChemical science2020
A kinetic description of how interfaces accelerate reactions in micro-compartments.
Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 41 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
41 citing papers in PubMed, 136 citations in OpenAlex.
- Rubrene-Oxalate Electrochemiluminescence Reveals Physicochemical Properties of Triphasic Boundaries.Chemical & biomedical imaging · 2026Article
- Rapid spontaneous generation of organosulfur from inorganic sulfur in atmospheric microdroplets.Nature communications · 2026Article
- Surface tension measurements reveal charge-driven surfactant depletion in microdroplets approaching the Rayleigh limit.Chemical science · 2026Article
- Measuring the Dynamic Nanometric Contact Radius of a Single Microdroplet on an Electrified Microinterface.Angewandte Chemie (International ed. in English) · 2026Article
- Enhancement of Esterification Reaction Rates in Solvent-Free Aerosol Droplets.Journal of the American Chemical Society · 2026Article
- Chemical Routes to Primitive Membranes: Prebiotic Lipid Formation at the Origin of Life.Life (Basel, Switzerland) · 2026Review
- Photoelectron imaging of substituted benzenes in aqueous aerosol droplets.Physical chemistry chemical physics : PCCP · 2026Article
- Highly efficient production of nitrite and nitrate from air at the gas-water interface of nanobubbles.Science advances · 2026Article
- Atmospheric Sampling Mass Spectrometers Activate and Ionize Neutral Water Microdroplets to MeV Energies and up to 200,000+ Charges: Implications for Water Stability and Unusual Chemistry in Microdroplets.ACS central science · 2025Article
- Ester Formation in Alcohol Microdroplet Sprays: Enhanced Reactivity of CThe journal of physical chemistry. A · 2025Article
- Role of Interfacial Processes in Accelerated Reactions in Nano- and Microdroplets.The journal of physical chemistry. A · 2025Article
- Evidence on Interfacial Reaction Governing NOEnvironmental science & technology · 2025Article
- Real-Time Visualization of an Elusive, Strong Reducing Agent during Tris(2,2'-bipyridyl)ruthenium(II) Electro-Oxidation in Water.Journal of the American Chemical Society · 2025Article
- Rapid and Sensitive Chemical Analysis of Individual Picolitre Droplets by Mass Spectrometry.Analytical chemistry · 2025Article
- The gas|liquid interface eclipses the liquid|liquid interface for glucose oxidase rate acceleration in microdroplets.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
- Model-Measurement Comparisons for Surfactant-Containing Aerosol Droplets.ACS earth & space chemistry · 2024Article
- Enhanced condensation kinetics in aqueous microdroplets driven by coupled surface reactions and gas-phase partitioning.Chemical science · 2024Article
- Reaction acceleration at the surface of a levitated droplet by vapor dosing from a partner droplet.Chemical science · 2024Article
- Observation of a chemical reaction in a levitating microdroplet cluster and droplet-generated music.Chemical science · 2024Article
- Surfactant Partitioning Dynamics in Freshly Generated Aerosol Droplets.Journal of the American Chemical Society · 2024Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
6 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A kinetic expression is derived to explain how interfaces alter bulk chemical equilibria and accelerate reactions in micro-compartments. This description, aided by the development of a stochastic model, quantitatively predicts previous experimental observations of accelerated imine synthesis in micron-sized emulsions. The expression accounts for how reactant concentration and compartment size together lead to accelerated reaction rates under micro-confinement. These rates do not depend solely on concentration, but rather the fraction of total molecules in the compartment that are at the interface. Although there are ∼10
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.