Evidence map›Paper›PMID 34122977›Full record

ArticleChemical science2020

Quantification of the mixed-valence and intervalence charge transfer properties of a cofacial metal-organic framework

Patrick W Doheny, Jack K Clegg, Floriana Tuna, David Collison, Cameron J Kepert, Deanna M D'Alessandro

Abstract read
In one paragraph

Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Review
  2. Article
  3. The Excited-State Creutz-Taube Ion.Angewandte Chemie (International ed. in English) · 2022
    Article
  4. Article
  5. Article
  6. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Patrick W DohenySchool of Chemistry, The University of Sydney New South Wales 2006 Australia deanna.dalessandro@sydney.edu.au cameron.kepert@sydney.edu.au +61 2 93513777.ORCID https://orcid.org/0000-0003-1705-8850
Jack K CleggSchool of Chemistry and Molecular Biosciences, The University of Queensland St Lucia Queensland 4072 Australia.ORCID https://orcid.org/0000-0002-7140-5596
Floriana TunaDepartment of Chemistry and Photon Science Institute, The University of Manchester Manchester M13 9PL UK.ORCID https://orcid.org/0000-0002-5541-1750
David CollisonDepartment of Chemistry and Photon Science Institute, The University of Manchester Manchester M13 9PL UK.
Cameron J KepertSchool of Chemistry, The University of Sydney New South Wales 2006 Australia deanna.dalessandro@sydney.edu.au cameron.kepert@sydney.edu.au +61 2 93513777.ORCID https://orcid.org/0000-0002-6105-9706
Deanna M D'AlessandroSchool of Chemistry, The University of Sydney New South Wales 2006 Australia deanna.dalessandro@sydney.edu.au cameron.kepert@sydney.edu.au +61 2 93513777.ORCID https://orcid.org/0000-0002-1497-2543

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Gaining a fundamental understanding of charge transfer mechanisms in three-dimensional Metal-Organic Frameworks (MOFs) is crucial to the development of electroactive and conductive porous materials. These materials have potential in applications in porous conductors, electrocatalysts and energy storage devices; however the structure-property relationships pertaining to charge transfer and its quantification are relatively poorly understood. Here, the cofacial Cd(ii)-based MOF [Cd(BPPTzTz)(tdc)]·2DMF (where BPPTzTz = 2,5-bis(4-(pyridin-4-yl)phenyl)thiazolo[5,4-

Identifiers

PMID34122977
PMCPMC8159307

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.