Evidence map›Paper›PMID 34122850›Full record

ArticleChemical science2020

Proton-coupled electron transfer across benzimidazole bridges in bioinspired proton wires.

Emmanuel Odella, S Jimena Mora, Brian L Wadsworth, Joshua J Goings, Miguel A Gervaldo, Leonides E Sereno, Thomas L Groy, Devens Gust, Thomas A Moore, Gary F Moore and 2 more

Open access · diamondAbstract read
In one paragraph

Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.

0numbers the graph read from it
0cells of the map it votes in
13citing papers in PubMed
1.2field-weighted citation impact, top 24% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

13 citing papers in PubMed, 33 citations in OpenAlex.

  1. Leveraging Multiproton-Coupled Electron Transfer to Improve Ir(III) Photocatalyst Efficiency.The journal of physical chemistry. C, Nanomaterials and interfaces · 2026
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors at 3 institutions in 2 countries.

Emmanuel OdellaSchool of Molecular Sciences, Arizona State University Tempe Arizona 85287-1604 USA gary.f.moore@asu.edu amoore@asu.edu.ORCID https://orcid.org/0000-0002-7021-400X
S Jimena MoraSchool of Molecular Sciences, Arizona State University Tempe Arizona 85287-1604 USA gary.f.moore@asu.edu amoore@asu.edu.ORCID https://orcid.org/0000-0003-4181-4732
Brian L WadsworthSchool of Molecular Sciences, Arizona State University Tempe Arizona 85287-1604 USA gary.f.moore@asu.edu amoore@asu.edu.ORCID https://orcid.org/0000-0002-0274-9993
Joshua J GoingsDepartment of Chemistry, Yale University New Haven Connecticut 06520-8107 USA sharon.hammes-schiffer@yale.edu.ORCID https://orcid.org/0000-0002-2817-1966
Miguel A GervaldoDepartamento de Química, Facultad de Ciencias Exactas, Físico-Químicas y Naturales, Universidad Nacional de Río Cuarto Agencia Postal No 3 5800 Río Cuarto Córdoba Argentina.ORCID https://orcid.org/0000-0001-9287-5872
Leonides E SerenoDepartamento de Química, Facultad de Ciencias Exactas, Físico-Químicas y Naturales, Universidad Nacional de Río Cuarto Agencia Postal No 3 5800 Río Cuarto Córdoba Argentina.ORCID https://orcid.org/0000-0001-8361-7695
Thomas L GroySchool of Molecular Sciences, Arizona State University Tempe Arizona 85287-1604 USA gary.f.moore@asu.edu amoore@asu.edu.ORCID https://orcid.org/0000-0002-0313-1116
Devens GustSchool of Molecular Sciences, Arizona State University Tempe Arizona 85287-1604 USA gary.f.moore@asu.edu amoore@asu.edu.ORCID https://orcid.org/0000-0003-0550-8498
Thomas A MooreSchool of Molecular Sciences, Arizona State University Tempe Arizona 85287-1604 USA gary.f.moore@asu.edu amoore@asu.edu.ORCID https://orcid.org/0000-0002-1577-7117
Gary F MooreSchool of Molecular Sciences, Arizona State University Tempe Arizona 85287-1604 USA gary.f.moore@asu.edu amoore@asu.edu.ORCID https://orcid.org/0000-0003-3369-9308
Sharon Hammes-SchifferDepartment of Chemistry, Yale University New Haven Connecticut 06520-8107 USA sharon.hammes-schiffer@yale.edu.ORCID https://orcid.org/0000-0002-3782-6995
Ana L MooreSchool of Molecular Sciences, Arizona State University Tempe Arizona 85287-1604 USA gary.f.moore@asu.edu amoore@asu.edu.ORCID https://orcid.org/0000-0002-6653-9506
Tempe Union High School District · USNational University of Río Cuarto · ARYale University · US

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Designing molecular platforms for controlling proton and electron movement in artificial photosynthetic systems is crucial to efficient catalysis and solar energy conversion. The transfer of both protons and electrons during a reaction is known as proton-coupled electron transfer (PCET) and is used by nature in myriad ways to provide low overpotential pathways for redox reactions and redox leveling, as well as to generate bioenergetic proton currents. Herein, we describe theoretical and electrochemical studies of a series of bioinspired benzimidazole-phenol (BIP) derivatives and a series of dibenzimidazole-phenol (BI

Identifiers

PMID34122850
PMCPMC8152432
OpenAlexW3012159850

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.