Evidence map›Paper›PMID 34113052›Full record

ArticleJournal of coordination chemistry2019

Tunable intramolecular multicenter H-bonding interactions in first-row metal complexes bearing bidentate redox-active ligands.

Khashayar Rajabimoghadam, Yousef Darwish, Umyeena Bashir, Dylan Pitman, Sidney Eichelberger, Maxime A Siegler, Isaac Garcia-Bosch

Abstract read
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In one paragraph

Article in Journal of coordination chemistry, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. A 4HJournal of the American Chemical Society · 2022
    Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Khashayar RajabimoghadamDepartment of Chemistry, Southern Methodist University, Dallas, TX, USA.
Yousef DarwishDepartment of Chemistry, Southern Methodist University, Dallas, TX, USA.
Umyeena BashirDepartment of Chemistry, Southern Methodist University, Dallas, TX, USA.
Dylan PitmanDepartment of Chemistry, Southern Methodist University, Dallas, TX, USA.
Sidney EichelbergerDepartment of Chemistry, Southern Methodist University, Dallas, TX, USA.
Maxime A SieglerJohns Hopkins University, Baltimore, MA, USA.
Isaac Garcia-BoschDepartment of Chemistry, Southern Methodist University, Dallas, TX, USA.

Funding

The role of leptin in autoimmune-associated hypertensionP20GM104357 · NIGMS · UNIVERSITY OF MISSISSIPPI MED CTR · PI TAYLOR, ERIN BASSFORD · 2013 to 2022
$23.4M
Bioinspired Copper-Promoted C-H HydroxylationsR15GM128078 · NIGMS · SOUTHERN METHODIST UNIVERSITY · PI GARCIA-BOSCH, ISAAC · 2018 to 2018
$415k
NIGMS NIH HHS P20 GM104357NIGMS NIH HHS R15 GM128078
6 · The paper itself

Abstract

In this research article, we report the synthesis and structural characterization of a family of first-row metal complexes bearing redox-active ligands with tunable H-bonding donors. We observed that these coordination complexes can adopt three different geometries and that they are stabilized by intramolecular multicenter H-bonding interactions, which are systematically modified by changing the metal ion (Co, Ni, Cu, Zn), the ligand scaffold (variations in the diamine and ureanyl substituents used) and the solvent of crystallization.

Indexed as

first-row transition metalsH-Bondingintramolecular multicenter H-bonding interactions

Identifiers

PMID34113052
PMCPMC8188844

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.