Evidence map›Paper›PMID 34099662›Full record

ArticleNature communications2021

Are Shockley-Read-Hall and ABC models valid for lead halide perovskites?

Alexander Kiligaridis, Pavel A Frantsuzov, Aymen Yangui, Sudipta Seth, Jun Li, Qingzhi An, Yana Vaynzof, Ivan G Scheblykin

Abstract read
In one paragraph

Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 24 papers.

0numbers the graph read from it
0cells of the map it votes in
24citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

24 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
  4. The critical role of surface dipoles in CsPbIEnergy & environmental science · 2026
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  5. Arm-Length-Controlled CsPbBrAdvanced materials (Deerfield Beach, Fla.) · 2026
    Article
  6. Article
  7. Article
  8. Review
  9. Article
  10. NIR Luminescence from Deep-Level Traps in CsPbBrThe journal of physical chemistry letters · 2025
    Article
  11. Article
  12. Article
  13. Article
  14. Review
  15. Article
  16. Effect of Single-Crystal TiOThe journal of physical chemistry letters · 2024
    Article
  17. Article
  18. Article
  19. Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Alexander KiligaridisChemical Physics and NanoLund, Lund University, P.O. Box 118, Lund, 22100, Sweden.
Pavel A FrantsuzovVoevodsky Institute of Chemical Kinetics and Combustion, Siberian Brunch of the Russian Academy of Science, Institutskaya 3, Novosibirsk, 630090, Russia. pavel.frantsuzov@gmail.com.ORCID http://orcid.org/0000-0002-7717-5453
Aymen YanguiChemical Physics and NanoLund, Lund University, P.O. Box 118, Lund, 22100, Sweden.ORCID http://orcid.org/0000-0002-6695-972X
Sudipta SethChemical Physics and NanoLund, Lund University, P.O. Box 118, Lund, 22100, Sweden.ORCID http://orcid.org/0000-0002-8666-4080
Jun LiChemical Physics and NanoLund, Lund University, P.O. Box 118, Lund, 22100, Sweden.ORCID http://orcid.org/0000-0002-0274-3989
Qingzhi AnIntegrated Center for Applied Physics and Photonic Materials (IAPP) and Centre for Advancing Electronics Dresden (CFAED), Technical University of Dresden, Dresden, Germany.ORCID http://orcid.org/0000-0003-0145-1332
Yana VaynzofIntegrated Center for Applied Physics and Photonic Materials (IAPP) and Centre for Advancing Electronics Dresden (CFAED), Technical University of Dresden, Dresden, Germany. yana.vaynzof@tu-dresden.de.ORCID http://orcid.org/0000-0002-0783-0707
Ivan G ScheblykinChemical Physics and NanoLund, Lund University, P.O. Box 118, Lund, 22100, Sweden. ivan.scheblykin@chemphys.lu.se.ORCID http://orcid.org/0000-0001-6059-4777

Funding

China Scholarship Council (CSC) 201608530162Deutsche Forschungsgemeinschaft (German Research Foundation) 424216076
6 · The paper itself

Abstract

Metal halide perovskites are an important class of emerging semiconductors. Their charge carrier dynamics is poorly understood due to limited knowledge of defect physics and charge carrier recombination mechanisms. Nevertheless, classical ABC and Shockley-Read-Hall (SRH) models are ubiquitously applied to perovskites without considering their validity. Herein, an advanced technique mapping photoluminescence quantum yield (PLQY) as a function of both the excitation pulse energy and repetition frequency is developed and employed to examine the validity of these models. While ABC and SRH fail to explain the charge dynamics in a broad range of conditions, the addition of Auger recombination and trapping to the SRH model enables a quantitative fitting of PLQY maps and low-power PL decay kinetics, and extracting trap concentrations and efficacies. However, PL kinetics at high power are too fast and cannot be explained. The proposed PLQY mapping technique is ideal for a comprehensive testing of theories and applicable to any semiconductor.

Identifiers

PMID34099662
PMCPMC8185072

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.