ArticleChemical science2020
A case of chain propagation: α-aminoalkyl radicals as initiators for aryl radical chemistry.
Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 30 papers.
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Who cites it
30 citing papers in PubMed, 128 citations in OpenAlex.
- Achieving Diverse Functionalizations of Electron-Deficient Aryl Halides via Carbonate-Mediated Electron-Donor-Acceptor Complexes.European journal of organic chemistry · 2026Article
- Photochemical reduction of aryl chlorides, bromides, and iodidesChemical science · 2026Article
- Base Metal Photocatalysts: A Bright Future in Photoredox Catalysis?Organometallics · 2026Article
- Article
- Monofluoromethyl Radical Mediated Halogen-Atom Transfer.Journal of the American Chemical Society · 2025Article
- Consecutive mechanical-force-induced electron transfer for reduction of aryl halides with high reduction potentials.Nature communications · 2025Article
- Base-Promoted Homolytic Aromatic Substitution (BHAS) Reactions and Hydrodehalogenations Driven by Green Light and an Iron(III)-NHC Photoredox Catalyst.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations.Chemical reviews · 2025Review
- Activation and C-C Coupling of Aryl Iodides via Bismuth Photocatalysis.Angewandte Chemie (International ed. in English) · 2025Article
- Photoinduced Intermolecular Radical Hydroalkylation of Olefins via Ligated Boryl Radicals-Mediated Halogen Atom Transfer.Organic letters · 2024Article
- Synergistic Merger of Ketone, Halogen Atom Transfer (XAT), and Nickel-Mediated C(spACS organic & inorganic Au · 2024Article
- Recent Advances in the Application of P(III)-Nucleophiles to Create New P-C Bonds through Michaelis-Arbuzov-Type Rearrangement.Topics in current chemistry (Cham) · 2024Review
- Site-selective and metal-free C-H phosphonation of arenesRSC advances · 2023Article
- Effective Formation of New C(spChemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Practical, scalable, and transition metal-free visible light-induced heteroarylation route to substituted oxindoles.Chemical science · 2023Article
- Photoinduced Halogen-Atom Transfer byJournal of the American Chemical Society · 2023Article
- Transition-metal free C-N bond formation from alkyl iodides and diazonium salts via halogen-atom transfer.Nature communications · 2022Article
- Photocatalytic direct borylation of carboxylic acids.Nature communications · 2022Article
- α-Thianthrenium Carbonyl Species: The Equivalent of an α-Carbonyl Carbocation.Angewandte Chemie (International ed. in English) · 2022Article
- Solvent Anions Enable Photoinduced Borylation and Phosphonation of Aryl Halides via EDA Complexes.Organic letters · 2022Article
Corrections and comments
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Authors and funding
4 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The generation of aryl radicals from the corresponding halides by redox chemistry is generally considered a difficult task due to their highly negative reduction potentials. Here we demonstrate that α-aminoalkyl radicals can be used as both initiators and chain-carriers for the radical coupling of aryl halides with pyrrole derivatives, a transformation often employed to evaluate new highly reducing photocatalysts. This mode of reactivity obviates for the use of strong reducing species and was also competent in the formation of sp
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.