ReviewChemical science2020
Defunctionalisation catalysed by boron Lewis acids.
Review in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
20 citing papers in PubMed, 77 citations in OpenAlex.
- Electrochemically driven deoxychlorination of aliphatic alcoholsChemical science · 2026Article
- Reductive Deoxygenation of Aromatic Aldehydes and Ketones with Boron Triiodide.The Journal of organic chemistry · 2026Article
- Triarylborane-Catalyzed Homogeneous Molecular Transformations Using Organic Reductants.Chemical reviews · 2026Article
- Room-Temperature Degradation of Lignin from Wasted Seed Coats for the Production of Pyrocatechol/Gallol Derivatives.ChemSusChem · 2026Article
- Rational design of super reductive EDA photocatalyst for challenging reactions: a theoretical and experimental study.RSC advances · 2024Article
- "Activated Borane": A Porous Borane Cluster Polymer as an Efficient Lewis Acid-Based Catalyst.ACS catalysis · 2023Article
- Tris(pentafluorophenyl)borane-catalyzed Hydride Transfer Reactions in Polysiloxane Chemistry-Piers-Rubinsztajn Reaction and Related Processes.Molecules (Basel, Switzerland) · 2023Review
- Atom-economic and stereoselective catalytic synthesis of fully substituted enol esters/carbonates of amides in acyclic systems enabled by boron Lewis acid catalysis.Chemical science · 2023Article
- Direct nucleophilic and electrophilic activation of alcohols using a unified boron-based organocatalyst scaffold.Nature communications · 2023Article
- An easy-to-perform evaluation of steric properties of Lewis acids.Chemical science · 2023Article
- Boron Lewis Acid Catalysis Enables the Direct Cyanation of Benzyl Alcohols by Means of Isonitrile as Cyanide Source.Molecules (Basel, Switzerland) · 2023Article
- Direct synthesis of sila-benzoazoles through hydrosilylation and rearrangement cascade reaction of benzoazoles and silanes.Nature communications · 2023Article
- Bonding Situation of σ-E-H Complexes in Transition Metal and Main Group Compounds.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Activation of Si-H and B-H bonds by Lewis acidic transition metals and p-block elements: same, but different.Chemical science · 2022Review
- Competition for Hydride Between Silicon and Boron: Synthesis and Characterization of a Hydroborane-Stabilized Silylium Ion.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Hydrogen-Bridged Oligosilanylsilyl Mono- and Oligosilanylsilyl Dications.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Borane-catalyzed cascade Friedel-Crafts alkylation/[1,5]-hydride transfer/Mannich cyclization to afford tetrahydroquinolines.Chemical science · 2022Article
- Mechanistic insights into reductive deamination with hydrosilanes catalyzed by B(CFrontiers in chemistry · 2022Article
- Borane-catalyzed selective dihydrosilylation of terminal alkynes: reaction development and mechanistic insight.Chemical science · 2021Article
- Bis(pertrifluoromethylcatecholato)silane: Extreme Lewis Acidity Broadens the Catalytic Portfolio of Silicon.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Selective defunctionalisation of organic molecules to valuable intermediates is a fundamentally important transformation in organic synthesis. Despite the advances made in efficient and selective defunctionalisation using transition-metal catalysis, the cost, toxicity, and non-renewable properties limit its application in industrial manufacturing processes. In this regard, boron Lewis acid catalysis has emerged as a powerful tool for the cleavage of carbon-heteroatom bonds. The ground-breaking finding is that the strong boron Lewis acid B(C
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.