ArticleChemical science2020
Preparation and characterization of the enol of acetamide: 1-aminoethenol, a high-energy prebiotic molecule.
Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- The enol of isobutyric acid.Chemical communications (Cambridge, England) · 2024Article
- CThe journal of physical chemistry. A · 2022Article
- 1,1,2-Ethenetriol: The Enol of Glycolic Acid, a High-Energy Prebiotic Molecule.Angewandte Chemie (International ed. in English) · 2021Article
- Advancing understanding of actinide(iii) (Ac, Am, Cm) aqueous complexation chemistry.Chemical science · 2021Article
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Authors and funding
3 authors.
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Abstract
Amide tautomers, which constitute the higher-energy amide bond linkage, not only are key for a variety of biological but also prebiotic processes. In this work, we present the gas-phase synthesis of 1-aminoethenol, the higher-energy tautomer of acetamide, that has not been spectroscopically identified to date. The title compound was prepared by flash vacuum pyrolysis of malonamic acid and was characterized employing matrix isolation infrared as well as ultraviolet/visible spectroscopy. Coupled-cluster computations at the AE-CCSD(T)/cc-pVTZ level of theory support the spectroscopic assignments. Upon photolysis at
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