Evidence map›Paper›PMID 34094434›Full record

ReviewChemical science2020

Ligand-protected gold/silver superatoms: current status and emerging trends.

Haru Hirai, Shun Ito, Shinjiro Takano, Kiichirou Koyasu, Tatsuya Tsukuda

Open access · diamondAbstract readReview
In one paragraph

Review in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.

0numbers the graph read from it
0cells of the map it votes in
21citing papers in PubMed
5.3field-weighted citation impact, top 3% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

21 citing papers in PubMed, 108 citations in OpenAlex.

  1. Review
  2. Article
  3. Article
  4. Article
  5. A Tetrahedral Silver-Rich Supercluster Composed of 8-Electron IrHJournal of the American Chemical Society · 2026
    Article
  6. Article
  7. Article
  8. Atomically Precise [CuJournal of the American Chemical Society · 2025
    Article
  9. Article
  10. PdAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024
    Article
  11. A Comprehensive Analysis of Luminescent Crystallized Cu Nanoclusters.The journal of physical chemistry letters · 2024
    Review
  12. RhScience advances · 2023
    Article
  13. NbNational science review · 2023
    Article
  14. From AuInorganic chemistry · 2023
    Article
  15. Article
  16. Article
  17. Electron Affinities of Ligated Icosahedral MThe journal of physical chemistry letters · 2022
    Article
  18. Article
  19. A Review of State of the Art in Phosphine Ligated Gold Clusters and Application in Catalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022
    Review
  20. A homoleptic alkynyl-protected [AgChemical science · 2021
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 2 institutions in 2 countries.

Haru HiraiDepartment of Chemistry, Graduate School of Science, The University of Tokyo 7-3-1 Hongo, Bunkyo-ku Tokyo 113-0033 Japan tsukuda@chem.s.u-tokyo.ac.jp.
Shun ItoDepartment of Chemistry, Graduate School of Science, The University of Tokyo 7-3-1 Hongo, Bunkyo-ku Tokyo 113-0033 Japan tsukuda@chem.s.u-tokyo.ac.jp.
Shinjiro TakanoDepartment of Chemistry, Graduate School of Science, The University of Tokyo 7-3-1 Hongo, Bunkyo-ku Tokyo 113-0033 Japan tsukuda@chem.s.u-tokyo.ac.jp.ORCID https://orcid.org/0000-0001-9262-5283
Kiichirou KoyasuDepartment of Chemistry, Graduate School of Science, The University of Tokyo 7-3-1 Hongo, Bunkyo-ku Tokyo 113-0033 Japan tsukuda@chem.s.u-tokyo.ac.jp.ORCID https://orcid.org/0000-0002-9106-0054
Tatsuya TsukudaDepartment of Chemistry, Graduate School of Science, The University of Tokyo 7-3-1 Hongo, Bunkyo-ku Tokyo 113-0033 Japan tsukuda@chem.s.u-tokyo.ac.jp.ORCID https://orcid.org/0000-0002-0190-6379
The University of Tokyo · JPKyoto University · JP

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Monolayer-protected gold/silver clusters have attracted much interest as nano-scale building units for novel functional materials owing to their nonbulk-like structures and size-specific properties. They can be viewed as ligand-protected superatoms because their magic stabilities and fundamental properties are well explained in the framework of the jellium model. In the last decade, the number of ligand-protected superatoms with atomically-defined structures has been increasing rapidly thanks to the well-established synthesis and structural determination by X-ray crystallography. This perspective summarizes the current status and emerging trends in synthesis and characterization of superatoms. The topics related to synthesis include (1) development of targeted synthesis based on transformation, (2) enhancement of robustness and synthetic yield for practical applications, and (3) development of controlled fusion and assembly of well-defined superatoms to create new properties. New characterization approaches are also introduced such as (1) mass spectrometry and laser spectroscopies in the gas phase, (2) determination of static and dynamic structures, and (3) computational analysis by machine learning. Finally, future challenges and prospects are discussed for further promotion and development of materials science of superatoms.

Identifiers

PMID34094434
PMCPMC8162828
OpenAlexW3094530827

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.