Evidence map›Paper›PMID 34094274›Full record

ArticleChemical science2020

Asymmetric allylic substitution-isomerization to axially chiral enamides

Chao Sun, Xiaotian Qi, Xiao-Long Min, Xue-Dan Bai, Peng Liu, Ying He

Abstract read
In one paragraph

Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.

0numbers the graph read from it
0cells of the map it votes in
14citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

14 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Article
  6. Review
  7. Review
  8. Article
  9. Asymmetric Synthesis of Axially Chiral C-N Atropisomers.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022
    Review
  10. Article
  11. Article
  12. Article
  13. Article
  14. A Mild and Highly Diastereoselective Preparation ofThe Journal of organic chemistry · 2021
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Chao SunSchool of Chemical Engineering, Nanjing University of Science & Technology Nanjing 210094 China yhe@njust.edu.cn.
Xiaotian QiDepartment of Chemistry, University of Pittsburgh Pittsburgh Pennsylvania 15260 USA pengliu@pitt.edu.
Xiao-Long MinSchool of Chemical Engineering, Nanjing University of Science & Technology Nanjing 210094 China yhe@njust.edu.cn.
Xue-Dan BaiSchool of Chemical Engineering, Nanjing University of Science & Technology Nanjing 210094 China yhe@njust.edu.cn.
Peng LiuDepartment of Chemistry, University of Pittsburgh Pittsburgh Pennsylvania 15260 USA pengliu@pitt.edu.ORCID https://orcid.org/0000-0002-8188-632X
Ying HeSchool of Chemical Engineering, Nanjing University of Science & Technology Nanjing 210094 China yhe@njust.edu.cn.ORCID https://orcid.org/0000-0001-9159-4606

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Axially chiral enamides bearing a N-C axis have been recently studied and were proposed to be valuable chiral building blocks, but a stereoselective synthesis has not been achieved. Here, we report the first enantioselective synthesis of axially chiral enamides

Identifiers

PMID34094274
PMCPMC8162293

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.