ArticleChemical science2020
Bouncing off walls - widths of exit channels from shallow minima can dominate selectivity control.
Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
6 citing papers in PubMed.
- Ab Initio Molecular Dynamics Simulations for Organic Chemists─It is About Time!Journal of the American Chemical Society · 2026Review
- Interplay between Energy and Entropy Mediates Ambimodal Selectivity of Cycloadditions.Journal of chemical theory and computation · 2024Article
- Analogies between photochemical reactions and ground-state post-transition-state bifurcations shed light on dynamical origins of selectivity.Nature chemistry · 2024Article
- A 21st Century View of Allowed and Forbidden Electrocyclic Reactions.The Journal of organic chemistry · 2024Article
- Metal-Free Arylation of Benzothiophenes at C4 by Activation as their Benzothiophene S-Oxides.Angewandte Chemie (International ed. in English) · 2023Article
- Understanding chemistry: from "heuristic (soft) explanations and reasoning by analogy" to "quantum chemistry".Chemical science · 2022Review
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A selectivity model based on the widths of pathways to competing products, rather than barrier heights, is formulated for the butadiene + allyl cation reaction. This model was arrived at
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.