ArticleChemical science2020
Origin of rate enhancement and asynchronicity in iminium catalyzed Diels-Alder reactions.
Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
What it found
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The trial behind it
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Who cites it
28 citing papers in PubMed, 73 citations in OpenAlex.
- Article
- Development of a Vinylated Cyclic Allene: A Fleeting Strained Diene for the Diels-Alder Reaction.Angewandte Chemie (International ed. in English) · 2025Article
- Straightforward Access to Pentafluorosulfanylated Phenols and Aminophenols via [4 + 2] Diels-Alder Cycloaddition Reaction.ACS organic & inorganic Au · 2025Article
- Transition-state aromaticity and its relationship with reactivity in pericyclic reactions.Beilstein journal of organic chemistry · 2025Article
- Origin of the Felkin-Anh(-Eisenstein) model: a quantitative rationalization of a seminal concept.Chemical science · 2024Article
- What defines electrophilicity in carbonyl compounds.Chemical science · 2024Article
- Click Organocatalysis: Acceleration of Azide-Alkyne Cycloadditions with Mutually Orthogonal Click Reactions.The Journal of organic chemistry · 2024Article
- Density Functional Theory Calculations: A Useful Tool to Investigate Mechanisms of 1,3-Dipolar Cycloaddition Reactions.International journal of molecular sciences · 2024Review
- Mechanistic Insights into the DABCO-Catalyzed Cloke-Wilson Rearrangement: A DFT Perspective.The Journal of organic chemistry · 2023Article
- Lewis Acid-Catalyzed Carbonyl-Ene Reaction: Interplay between Aromaticity, Synchronicity, and Pauli Repulsion.The Journal of organic chemistry · 2023Article
- ηChemistry, an Asian journal · 2023Article
- How Bases Catalyze Diels-Alder Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Rational Tuning of the Reactivity of Three-Membered Heterocycle Ring Openings via SChemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Pericyclic reaction benchmarks: hierarchical computations targeting CCSDT(Q)/CBS and analysis of DFT performance.Physical chemistry chemical physics : PCCP · 2022Article
- How Ionization Catalyzes Diels-Alder Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Origin of Catalysis and Selectivity in Lewis Acid-Promoted Diels-Alder Reactions Involving Vinylazaarenes as Dienophiles.The Journal of organic chemistry · 2022Article
- An ETS-NOCV-based computational strategies for the characterization of concerted transition states involving COJournal of computational chemistry · 2022Article
- Hydrogen-Bond-Assisted Diels-Alder Kinetics or Self-Healing in Reversible Polymer Networks? A Combined Experimental and Theoretical Study.Molecules (Basel, Switzerland) · 2022Article
- Origin of asynchronicity in Diels-Alder reactions.Physical chemistry chemical physics : PCCP · 2021Article
- Switch From Pauli-Lowering to LUMO-Lowering Catalysis in Brønsted Acid-Catalyzed Aza-Diels-Alder Reactions.ChemistryOpen · 2021Article
Corrections and comments
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Authors and funding
4 authors at 3 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The Diels-Alder reactions between cyclopentadiene and various α,β-unsaturated aldehyde, imine, and iminium dienophiles were quantum chemically studied using a combined density functional theory and coupled-cluster theory approach. Simple iminium catalysts accelerate the Diels-Alder reactions by lowering the reaction barrier up to 20 kcal mol
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.