Evidence map›Paper›PMID 34094168›Full record

ArticleChemical science2020

The precise editing of surface sites on a molecular-like gold catalyst for modulating regioselectivity.

Shuohao Li, Hongwei Chen, Xu Liu, Haoqi Liu, Jing Ma, Yan Zhu

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Review
  2. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Shuohao LiSchool of Chemistry and Chemical Engineering, Nanjing University Nanjing 210093 China zhuyan@nju.edu.cn majing@nju.edu.cn.
Hongwei ChenSchool of Chemistry and Chemical Engineering, Nanjing University Nanjing 210093 China zhuyan@nju.edu.cn majing@nju.edu.cn.
Xu LiuSchool of Chemistry and Chemical Engineering, Nanjing University Nanjing 210093 China zhuyan@nju.edu.cn majing@nju.edu.cn.ORCID https://orcid.org/0000-0002-0842-1075
Haoqi LiuSchool of Chemistry and Chemical Engineering, Nanjing University Nanjing 210093 China zhuyan@nju.edu.cn majing@nju.edu.cn.
Jing MaSchool of Chemistry and Chemical Engineering, Nanjing University Nanjing 210093 China zhuyan@nju.edu.cn majing@nju.edu.cn.ORCID https://orcid.org/0000-0001-5848-9775
Yan ZhuSchool of Chemistry and Chemical Engineering, Nanjing University Nanjing 210093 China zhuyan@nju.edu.cn majing@nju.edu.cn.ORCID https://orcid.org/0000-0002-5993-4110

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

It is extremely difficult to precisely edit a surface site on a typical nanoparticle catalyst without changing other parts of the catalyst. This precludes a full understanding of which site primarily determines the catalytic properties. Here, we couple experimental data collection with theoretical analysis to correlate rich structural information relating to atomically precise gold clusters with the catalytic performance for the click reaction of phenylacetylene and benzyl azide. We also identify a specific surface site that is capable of achieving high regioselectivity. We further conduct site-specific editing on a thiolate-protected gold cluster by peeling off two monomeric RS-Au-SR motifs and replacing them with two Ph

Identifiers

PMID34094168
PMCPMC8163066

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.