Evidence map›Paper›PMID 34094165›Full record

ArticleChemical science2020

Broadband fluorescence reveals mechanistic differences in excited-state proton transfer to protic and aprotic solvents.

Pragya Verma, Arnulf Rosspeintner, Bogdan Dereka, Eric Vauthey, Tatu Kumpulainen

Open access · diamondAbstract read
In one paragraph

Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
3.5field-weighted citation impact, top 8% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed, 25 citations in OpenAlex.

  1. Pyrazine-Functionalized Ru(II)-Complexes as Visible-Light Activated Photobases.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025
    Article
  2. Boramidine: a boron-based photoacidic fluorophore.Chemical communications (Cambridge, England) · 2025
    Article
  3. Review
  4. Article
  5. pH Jumps in a Protic Ionic Liquid Proceed by Vehicular Proton Transport.The journal of physical chemistry letters · 2022
    Article
  6. Article
  7. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 1 institution in 1 country.

Pragya VermaDepartment of Physical Chemistry, University of Geneva 30 Quai Ernest Ansermet Geneva Switzerland Tatu.Kumpulainen@unige.ch +41 22 379 65 18 +41 22 379 36 58.ORCID https://orcid.org/0000-0002-9173-6982
Arnulf RosspeintnerDepartment of Physical Chemistry, University of Geneva 30 Quai Ernest Ansermet Geneva Switzerland Tatu.Kumpulainen@unige.ch +41 22 379 65 18 +41 22 379 36 58.ORCID https://orcid.org/0000-0002-1828-5206
Bogdan DerekaDepartment of Physical Chemistry, University of Geneva 30 Quai Ernest Ansermet Geneva Switzerland Tatu.Kumpulainen@unige.ch +41 22 379 65 18 +41 22 379 36 58.ORCID https://orcid.org/0000-0003-2895-7915
Eric VautheyDepartment of Physical Chemistry, University of Geneva 30 Quai Ernest Ansermet Geneva Switzerland Tatu.Kumpulainen@unige.ch +41 22 379 65 18 +41 22 379 36 58.ORCID https://orcid.org/0000-0002-9580-9683
Tatu KumpulainenDepartment of Physical Chemistry, University of Geneva 30 Quai Ernest Ansermet Geneva Switzerland Tatu.Kumpulainen@unige.ch +41 22 379 65 18 +41 22 379 36 58.ORCID https://orcid.org/0000-0001-9469-9294
University of Geneva · CH

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Excited-state proton transfer (ESPT) to solvent is often explained according to the two-step Eigen-Weller model including a contact ion pair (CIP*) as an intermediate, but general applicability of the model has not been thoroughly examined. Furthermore, examples of the spectral identification of CIP* are scarce. Here, we report on a detailed investigation of ESPT to protic (H

Identifiers

PMID34094165
PMCPMC8163259
OpenAlexW3041821287

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.