ArticleACS applied nano materials2019
Isolated Effects of Surface Ligand Density on the Catalytic Activity and Selectivity of Palladium Nanoparticles.
Article in ACS applied nano materials, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Catalytic Activity of Water-Soluble Palladium Nanoparticles with Anionic and Cationic Capping Ligands for Reduction, Oxidation, and C-C Coupling Reactions in Water.Nanomaterials (Basel, Switzerland) · 2025Article
- Water-Soluble Pd Nanoparticles for the Anti-Markovnikov Oxidation of Allyl Benzene in Water.Nanomaterials (Basel, Switzerland) · 2023Article
- Effects of lipid bilayer encapsulation and lipid composition on the catalytic activity and colloidal stability of hydrophobic palladium nanoparticles in water.RSC advances · 2022Article
- Analyzing the surface of functional nanomaterials-how to quantify the total and derivatizable number of functional groups and ligands.Mikrochimica acta · 2021Review
- Water-Soluble Noble Metal Nanoparticle Catalysts Capped with Small Organic Molecules for Organic Transformations in Water.ACS applied nano materials · 2021Article
- Proximity Effects of Methyl Group on Ligand Steric Interactions and Colloidal Stability of Palladium Nanoparticles.Frontiers in chemistry · 2020Article
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Authors and funding
3 authors.
Funding
Abstract
Alkanethiolate-capped palladium nanoparticles (PdNPs) have previously been synthesized by using a modified Brust-Schiffrin synthesis (using alkanethiosulfate instead of alkanethiol), in which the nanoparticle core size is established during alkanethiosulfate ligand passivation of the nanoparticle nucleation-growth initiated by borohydride reduction. Because of the dependence of core size on the amount of ligand present, surface ligand density decreases with increasing core size. Herein we present a method in which the core size is established independent of ligand addition, allowing the formation of PdNPs with similar core sizes yet different surface ligand densities. In this method, the core size is established during the temporary passivation of growing nanoparticles by borohydride and tetra-
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