ArticleChemical science2020
Photoexcited Pd(ii) auxiliaries enable light-induced control in C(sp
Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
10 citing papers in PubMed, 35 citations in OpenAlex.
- Illuminating Palladium Catalysis.Accounts of chemical research · 2025Article
- Palladium-catalyzed remote internal C(spNature communications · 2024Article
- Visible light-induced palladium-carbon bond weakening in catalytically relevant T-shaped complexes.Chemical science · 2023Article
- Kinetics of ligand exchange in solution: a quantitative mass spectrometry approach.Chemical science · 2023Article
- Article
- Multi-Resonant Thermally Activated Delayed Fluorescent (MR-TADF) Compounds as Photocatalysts.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Visible Light-Induced Transition Metal Catalysis.Chemical reviews · 2022Review
- Transition-Metal-Catalyzed, Coordination-Assisted Functionalization of Nonactivated C(spChemical reviews · 2021Review
- Photoinduced Palladium-Catalyzed Dicarbofunctionalization of Terminal Alkynes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Identifying reactive intermediates by mass spectrometry.Chemical science · 2020Review
Corrections and comments
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Authors and funding
7 authors at 3 institutions in 3 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Herein we report the photophysical and photochemical properties of palladacycle complexes derived from 8-aminoquinoline ligands, commonly used auxiliaries in C-H activation. Spectroscopic, electrochemical and computational studies reveal that visible light irradiation induces a mixed LLCT/MLCT charge transfer providing access to synthetically relevant Pd(iii)/Pd(iv) redox couples. The Pd(ii) complex undergoes photoinduced electron transfer with alkyl halides generating C(sp
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.