ArticleChemical science2020
Versatility and adaptative behaviour of the P^N chelating ligand MeDalphos within gold(i) π complexes.
Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
15 citing papers in PubMed, 56 citations in OpenAlex.
- Mechanism-Guided, Data-Driven Discovery of a Dinuclear Gold Catalyst for Promoting Oxidative Addition.Angewandte Chemie (International ed. in English) · 2026Article
- StereoselectiveACS organic & inorganic Au · 2025Article
- Article
- Nucleophilic Addition versus Migratory Insertion Pathways in the Gold-Catalyzed Heck Reaction: A Computational Study.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- π-Bonding of Group 11 Metals to a Tantalum Alkylidyne Alkyl Complex Promotes Unusual Tautomerism to Bis-alkylidene and COJournal of the American Chemical Society · 2024Article
- A Hemilabile NHC-Gold Complex and its Application to the Redox Neutral 1,2-Oxyarylation of Feedstock Alkenes.Angewandte Chemie (International ed. in English) · 2023Article
- Reductive Elimination Reactions in Gold(III) Complexes Leading to C(spInorganic chemistry · 2023Article
- Ligand-enabled oxidation of gold(i) complexes withChemical science · 2022Article
- Gold(I) α-Trifluoromethyl Carbenes: Synthesis, Characterization and Reactivity Studies.Angewandte Chemie (International ed. in English) · 2022Article
- Dicoordinate Au(I)-Ethylene Complexes as Hydroamination Catalysts.ACS catalysis · 2022Article
- A Systematic Study of the Effects of Complex Structure on Aryl Iodide Oxidative Addition at Bipyridyl-Ligated Gold(I) Centers.Angewandte Chemie (International ed. in English) · 2021Article
- A dicoordinate gold(I)-ethylene complex.Chemical communications (Cambridge, England) · 2021Article
- Gold(I) and Silver(I) π-Complexes with Unsaturated Hydrocarbons.Organometallics · 2021Article
- Group 11 Borataalkene Complexes: Models for Alkene Activation.Angewandte Chemie (International ed. in English) · 2021Article
- Oxidative additions of alkynyl/vinyl iodides to gold and gold-catalyzed vinylation reactions triggered by the MeDalphos ligand.Chemical science · 2021Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
6 authors at 3 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The hemilabile P^N ligand MeDalphos enables access to a wide range of stable gold(i) π-complexes with unbiased alkenes and alkynes, as well as electron-rich alkenes and for the first time electron-poor ones. All complexes have been characterized by multi-nuclear NMR spectroscopy and whenever possible, by X-ray diffraction analyses. They all adopt a rare tricoordinate environment around gold(i), with chelation of the P^N ligand and side-on coordination of the alkene, including the electron-rich one, 3,4-dihydro-2
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.