Rheological properties of calcite oozes: Implications for the fossilisation in the plattenkalks of the Solnhofen-Eichstätt lagoons in the Franconian Alb, Germany.

We report on an experimental study to investigate the sedimentation behaviour and rheological properties of extremely fine-grained calcite oozes. The experiments are aimed at clarifying if thixotropic behaviour may have played a role in the preservation of marine biota in plattenkalks of the Solnhofen lagoons of the Franconian Alb. Calcite particles with grain sizes from 2.2 to 4.4 μm were sedimented from water, seawater proxies, and hypersaline brines with up to 14 wt.% NaCl, for 170 days. High salinities as envisioned for the bottom waters of some Solnhofen lagoons slow down settling rates of calcite and may produce plattenkalks more porous and more friable than plattenkalks elsewhere in the Solnhofen archipelago. Rheological properties of calcite suspensions were measured with an oscillation rheometer. Calcite oozes with 40 vol.% calcite in suspension behave thixotropically regardless of the salinity of the pore solutions. Thixotropic behaviour may have the potential to promote the fossilisation of marine biota. Even if the sediment cover is thin, i.e. a few millimeters, a carcass covered by a thixotropic sediment would be largely isolated from the overlying water column because pore solutions in thixotropic media hardly communicate with the overlying water column. A fish carcass covered by a thixotropic sediment could impose local-scale physicochemical conditions on its direct sedimentary envelope favourable for preservation and the replacement of organic material by inorganic materials.