ArticleInternational journal of molecular sciences2021
Influence of Alkyl Chain Length on Thermal Properties, Structure, and Self-Diffusion Coefficients of Alkyltriethylammonium-Based Ionic Liquids.
Article in International journal of molecular sciences, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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Who cites it
9 citing papers in PubMed.
- Sulfonylimide-Based Single-Ion-Conducting Porous Organic Polymer Electrolytes for Enhanced Performance of Solid-State Lithium Batteries.ACS applied materials & interfaces · 2026Article
- Effect of Cation Symmetry on the Long-Range Ordering in Ionic Liquid Films.Langmuir : the ACS journal of surfaces and colloids · 2026Article
- Molecular Design Considerations for Azobenzene Anolytes.ACS omega · 2025Article
- Crystallization Kinetics of Phosphonium Ionic Liquids: Effect of Cation Alkyl Chain Length and Thermal History.The journal of physical chemistry. B · 2024Article
- Ionic liquid-coated lipid nanoparticles increase siRNA uptake into CNS targets.Nanoscale advances · 2024Article
- Relative Cation-Anion Diffusion in Alkyltriethylammonium-Based Ionic Liquids.International journal of molecular sciences · 2022Article
- Relationship between Translational and Rotational Dynamics of Alkyltriethylammonium-Based Ionic Liquids.International journal of molecular sciences · 2022Article
- Internal Dynamics of Ionic Liquids over a Broad Temperature Range-The Role of the Cation Structure.Materials (Basel, Switzerland) · 2021Article
- Correlated Dynamics in Ionic Liquids by Means of NMR Relaxometry: Butyltriethylammonium bis(Trifluoromethanesulfonyl)imide as an Example.International journal of molecular sciences · 2021Article
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
The application of ionic liquids (ILs) has grown enormously, from their use as simple solvents, catalysts, media in separation science, or electrolytes to that as task-specific, tunable molecular machines with appropriate properties. A thorough understanding of these properties and structure-property relationships is needed to fully exploit their potential, open new directions in IL-based research and, finally, properly implement the appropriate applications. In this work, we investigated the structure-properties relationships of a series of alkyltriethylammonium bis(trifluoromethanesulfonyl)imide [TEA-R][TFSI] ionic liquids in relation to their thermal behavior, structure organization, and self-diffusion coefficients in the bulk state using DSC, FT-IR, SAXS, and NMR diffusometry techniques. The phase transition temperatures were determined, indicating alkyl chain dependency. Fourier-transformed infrared spectroscopy studies revealed the structuration of the ionic liquids along with alkyl chain elongation. SAXS experiments clearly demonstrated the existence of polar/non-polar domains. The alkyl chain length influenced the expansion of the non-polar domains, leading to the expansion between cation heads in polar regions of the structured IL.
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Registered trials
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