ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021
Bioinspired Ether Cyclizations within a π-Basic Capsule Compared to Autocatalysis on π-Acidic Surfaces and Pnictogen-Bonding Catalysts.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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13 citing papers in PubMed.
- Pnictogen-bonding-crosslinked polymer networks: constructing self-healing materials.Chemical science · 2026Article
- Pnictogen-Bonding Catalysis: Copolymerization of COACS catalysis · 2025Article
- Pnictogen bonding enabled photosynthesis of chiral selenium-containing pyridines from pyridylphosphonium salts.Fundamental research · 2025Article
- Steric Selection of Anion Binding Sites by Organoantimony(V) Pnictogen Bond Donors: An Experimental and Computational Study.Inorganic chemistry · 2024Article
- Evaluation of Concomitant Halogen and Pnictogen Bonds in Cocrystals of Imines Derived from 2-Nitrobenzaldehyde and 4-Haloaniline.Crystal growth & design · 2024Article
- The Origin of Anion-π Autocatalysis.JACS Au · 2023Article
- Are ArOrganometallics · 2023Article
- Anion-π catalysis on carbon allotropes.Beilstein journal of organic chemistry · 2023Review
- Decoded fingerprints of hyperresponsive, expanding product space: polyether cascade cyclizations as tools to elucidate supramolecular catalysis.Chemical science · 2022Article
- A resorcin[4]arene hexameric capsule as a supramolecular catalyst in elimination and isomerization reactions.Beilstein journal of organic chemistry · 2022Article
- On the Importance of Pnictogen and Chalcogen Bonding Interactions in Supramolecular Catalysis.International journal of molecular sciences · 2021Review
- Pnictogen-Bonding Catalysis and Transport Combined: Polyether Transporters Made In Situ.JACS Au · 2021Article
- Bioinspired Ether Cyclizations within a π-Basic Capsule Compared to Autocatalysis on π-Acidic Surfaces and Pnictogen-Bonding Catalysts.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
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9 authors.
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Abstract
While the integration of supramolecular principles in catalysis attracts increasing attention, a direct comparative assessment of the resulting systems catalysts to work out distinct characteristics is often difficult. Herein is reported how the broad responsiveness of ether cyclizations to diverse inputs promises to fill this gap. Cyclizations in the confined, π-basic and Brønsted acidic interior of supramolecular capsules, for instance, are found to excel with speed (exceeding general Brønsted acid and hydrogen-bonding catalysts by far) and selective violations of the Baldwin rules (as extreme as the so far unique pnictogen-bonding catalysts). The complementary cyclization on π-acidic aromatic surfaces remains unique with regard to autocatalysis, which is shown to be chemo- and diastereoselective with regard to product-like co-catalysts but, so far, not enantioselective.
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