ReviewNature communications2021
Advances in heterometallic ring-opening (co)polymerisation catalysis.
Review in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
19 citing papers in PubMed.
- Temperature-Driven Switching Between Block, Near-Statistical, and Gradient Copolymers Enabled by Multinuclear Aluminum Catalysis.Macromolecular rapid communications · 2026Article
- (AB)Macromolecules · 2025Article
- Monomer-Dependent Selectivity in Sulfur-Containing Ring-Opening Copolymerisation: Bimetallic Catalysis for Predictive Design of Degradable Polymers.Angewandte Chemie (International ed. in English) · 2025Article
- Highly Stable Heterometallic Catalysts for Polyester Depolymerization and Polymerization at High Temperatures.Journal of the American Chemical Society · 2025Article
- General, Quantified Structure-Performance Correlations for Synergistic Heteronuclear Electro‑, Polymerization, and Asymmetric Catalysts.ACS catalysis · 2025Review
- Sequence Control in Sulphur-Containing Ring-Opening Co- and Terpolymerisations.Angewandte Chemie (International ed. in English) · 2025Review
- Synergic Catalysis: the Importance of Intermetallic Separation in Co(III)K(I) Catalysts for Ring Opening Copolymerizations.Journal of the American Chemical Society · 2024Article
- Controlled Carbon Dioxide Terpolymerizations to Deliver Toughened yet Recyclable Thermoplastics.Macromolecules · 2024Article
- Exploiting Multimetallic Cooperativity in the Ring-Opening Polymerization of Cyclic Esters and Ethers.ACS catalysis · 2024Review
- Multinuclear Zinc-Magnesium Hydroxide Carboxylates: A Predesigned Model System for Copolymerization of COInorganic chemistry · 2023Article
- Development of Heterobimetallic Al/Mg Complexes for the Very Rapid Ring-Opening Polymerization of Lactides.Inorganic chemistry · 2023Article
- Cationic tetranuclear macrocyclic CaCoChemical science · 2023Article
- Understanding catalytic synergy in dinuclear polymerization catalysts for sustainable polymers.Nature communications · 2023Article
- Injectable and photocurable macromonomers synthesized using a heterometallic magnesium-titanium metal-organic catalyst for elastomeric polymer networks.RSC advances · 2023Article
- Added Complexity!-Mechanistic Aspects of Heterobimetallic Complexes for Application in Homogeneous Catalysis.Molecules (Basel, Switzerland) · 2023Review
- Synthesis and Characterization of Zinc(II), Cadmium(II), and Palladium(II) Complexes with the Thiophene-Derived Schiff Base Ligand.ACS omega · 2023Article
- Sustainability and Polyesters: Beyond Metals and Monomers to Function and Fate.Accounts of chemical research · 2022Article
- Lithium achieves sequence selective ring-opening terpolymerisation (ROTERP) of ternary monomer mixtures.Chemical science · 2022Article
- Scaffold printing using biodegradable poly(1,4-butylene carbonate) ink: printability,Materials today. Bio · 2021Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Truly sustainable plastics require renewable feedstocks coupled with efficient production and end-of-life degradation/recycling processes. Some of the most useful degradable materials are aliphatic polyesters, polycarbonates and polyamides, which are often prepared via ring-opening (co)polymerisation (RO(CO)P) using an organometallic catalyst. While there has been extensive research into ligand development, heterometallic cooperativity offers an equally promising yet underexplored strategy to improve catalyst performance, as heterometallic catalysts often exhibit significant activity and selectivity enhancements compared to their homometallic counterparts. This review describes advances in heterometallic RO(CO)P catalyst design, highlighting the overarching structure-activity trends and reactivity patterns to inform future catalyst design.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.