ReviewACS central science2021
Borrowing Hydrogen for Organic Synthesis.
Review in ACS central science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 56 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
56 citing papers in PubMed.
- Sustainable Routes Toward Amino Acid-Based Surfactants: Borrowing Hydrogen Catalysis and Beyond.ChemSusChem · 2026Article
- Article
- Phosphine-Free NNN Bis-Iminopyridine Supported Zinc(II) Catalysts: A Sustainable Platform for C─C Bond Formation Reactions via Borrowing Hydrogen Approach of Primary Alcohols.Chemistry, an Asian journal · 2026Article
- Electrochemically driven deoxychlorination of aliphatic alcoholsChemical science · 2026Article
- Copper-catalyzed and Y(OTf)RSC advances · 2026Article
- Remodified Ni/AlACS omega · 2026Article
- Molybdenum-Catalyzed One-Step Synthesis of Tetrahydroquinolines.Precision chemistry · 2026Article
- Methylene-Linked Triazolylidenes as Cooperative Ligands in Manganese-CatalyzedInorganic chemistry · 2026Article
- A universal atomically dispersed cobalt catalyst for alkylation of ketones alcohols and lignin-derived compounds.Nature communications · 2026Article
- Asymmetric Catalysis: Recent Advances toward a More Sustainable Synthesis.ACS central science · 2026Review
- The Diarylprolinol Silyl Ethers: After 20 Years Still Opening New Doors in Asymmetric Catalysis.Angewandte Chemie (International ed. in English) · 2026Review
- Room-Temperature Metal-Catalyzed Hydrogen Borrowing Alkylation.ACS catalysis · 2026Review
- Chemoselective Synthesis of δ-Amino Alcohols from Chiral 1,4-Diols Catalyzed by an NHC-Ir(III) Complex.Organic letters · 2026Article
- Single-Step Synthesis of 1,2-Cyclopentanediones by Dehydrogenative Annulation of Ethylene Glycol with Secondary Alcohols.Journal of the American Chemical Society · 2025Article
- CoACS organic & inorganic Au · 2025Article
- Iron Single-Atom Catalyzed N-Alkylation of Amines with Alcohols via Solvent-Free Borrowing Hydrogen Strategy.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- A comprehensive review on the silane-acid reduction of alkenes in organic synthesis.RSC advances · 2025Review
- Acid-promoted dehydroxylation coupling of aryl alcohols with 1,3-dicarbonyls and sulfonamides.BMC chemistry · 2025Article
- Deoxygenative C(Journal of the American Chemical Society · 2025Article
- Recent Developments in Borrowing Hydrogen Methodology in N-alkylation of Amines.Topics in current chemistry (Cham) · 2025Review
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Borrowing hydrogen is a process that is used to diversify the synthetic utility of commodity alcohols. A catalyst first oxidizes an alcohol by removing hydrogen to form a reactive carbonyl compound. This intermediate can undergo a diverse range of subsequent transformations before the catalyst returns the "borrowed" hydrogen to liberate the product and regenerate the catalyst. In this way, alcohols may be used as alkylating agents whereby the sole byproduct of this one-pot reaction is water. In recent decades, significant advances have been made in this area, demonstrating many effective methods to access valuable products. This outlook highlights the diversity of metal and biocatalysts that are available for this approach, as well as the various transformations that can be performed, focusing on a selection of the most significant and recent advances. By succinctly describing and conveying the versatility of borrowing hydrogen chemistry, we anticipate its uptake will increase across a wider scientific audience, expanding opportunities for further development.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.