ArticleNature communications2021
Electrosynthesis of 1,4-bis(diphenylphosphanyl) tetrasulfide via sulfur radical addition as cathode material for rechargeable lithium battery.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Disulfide-Assisted Organic Polysulfide Cathode Design Enables Improved Kinetics in Lithium-Sulfur Batteries.Small science · 2026Article
- Ionically conducting Li- and Na-phosphonates as organic electrode materials for rechargeable batteries.Chemical science · 2025Article
- Growing highly ordered Pt and Mn bimetallic single atomic layers over graphdiyne.Nature communications · 2024Article
- Understanding Reactive Sulfur Species through P/S Synergy.Inorganic chemistry · 2023Article
- Nano-sulfur confined in a 3D carbon nanotube/graphene network as a free-standing cathode for high-performance Li-S batteries.Nanoscale advances · 2022Article
- Carbon disulfide: A redox mediator for organodisulfides in redox flow batteries.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- A nitroaromatic cathode with an ultrahigh energy density based on six-electron reaction per nitro group for lithium batteries.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- Advances of Organosulfur Materials for Rechargeable Metal Batteries.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Review
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Organic electrodes are promising as next generation energy storage materials originating from their enormous chemical diversity and electrochemical specificity. Although organic synthesis methods have been extended to a broad range, facile and selective methods are still needed to expose the corners of chemical space. Herein, we report the organopolysulfide, 1,4-bis(diphenylphosphanyl)tetrasulfide, which is synthesized by electrochemical oxidation of diphenyl dithiophosphinic acid featuring the cleavage of a P-S single bond and a sulfur radical addition reaction. Density functional theory proves that the external electric field triggers the intramolecular rearrangement of diphenyl dithiophosphinic acid through dehydrogenation and sulfur migration along the P-S bond axis. Impressively, the Li/bis(diphenylphosphanyl)tetrasulfide cell exhibits the high discharge voltage of 2.9 V and stable cycling performance of 500 cycles with the capacity retention of 74.8%. Detailed characterizations confirm the reversible lithiation/delithiation process. This work demonstrates that electrochemical synthesis offers the approach for the preparation of advanced functional materials.
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Registered trials
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