Evidence map›Paper›PMID 34043353›Full record

ArticleInorganic chemistry2021

[2Fe-2S] Cluster Supported by Redox-Active

Qiuming Liang, Joshua C DeMuth, Aleksa Radović, Nikki J Wolford, Michael L Neidig, Datong Song

Abstract read
In one paragraph

Article in Inorganic chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Review
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Qiuming LiangDavenport Chemical Research Laboratories, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada.
Joshua C DeMuthDepartment of Chemistry, University of Rochester, Rochester, New York 14627, United States.
Aleksa RadovićDepartment of Chemistry, University of Rochester, Rochester, New York 14627, United States.
Nikki J WolfordDepartment of Chemistry, University of Rochester, Rochester, New York 14627, United States.
Michael L NeidigDepartment of Chemistry, University of Rochester, Rochester, New York 14627, United States.ORCID https://orcid.org/0000-0002-2300-3867
Datong SongDavenport Chemical Research Laboratories, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada.ORCID https://orcid.org/0000-0001-6622-5980

Funding

Iron-Catalyzed Cross-CouplingR01GM111480 · NIGMS · UNIVERSITY OF ROCHESTER · PI NEIDIG, MICHAEL L · 2014 to 2022
$3.1M
NIGMS NIH HHS R01 GM111480
6 · The paper itself

Abstract

As prevalent cofactors in living organisms, iron-sulfur clusters participate in not only the electron-transfer processes but also the biosynthesis of other cofactors. Many synthetic iron-sulfur clusters have been used in model studies, aiming to mimic their biological functions and to gain mechanistic insight into the related biological systems. The smallest [2Fe-2S] clusters are typically used for one-electron processes because of their limited capacity. Our group is interested in functionalizing small iron-sulfur clusters with redox-active ligands to enhance their electron storage capacity, because such functionalized clusters can potentially mediate multielectron chemical transformations. Herein we report the synthesis, structural characterization, and catalytic activity of a diferric [2Fe-2S] cluster functionalized with two

Indexed as

CatalysisIron-Sulfur ProteinsLigandsMolecular StructureNitrogenOxidation-ReductionPhenylenediamines1,2-diaminobenzeneIron-Sulfur ProteinsLigandsNitrogenPhenylenediamines

Identifiers

PMID34043353
PMCPMC8453056

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.