Evidence map›Paper›PMID 34038613›Full record

ArticleAngewandte Chemie (International ed. in English)2021

Hierarchical Superstructures by Combining Crystallization-Driven and Molecular Self-Assembly.

Andreas Frank, Christian Hils, Melina Weber, Klaus Kreger, Holger Schmalz, Hans-Werner Schmidt

Open access · hybridAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
1.7field-weighted citation impact, top 17% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed, 28 citations in OpenAlex.

  1. Review
  2. Review
  3. Controlling Helical Asymmetry in Supramolecular Copolymers byJournal of the American Chemical Society · 2023
    Article
  4. Visualizing molecular weights differences in supramolecular polymers.Proceedings of the National Academy of Sciences of the United States of America · 2022
    Article
  5. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 1 institution in 1 country.

Andreas FrankMacromolecular Chemistry I, University of Bayreuth and Bavarian Polymer Institute, Universitätsstrasse 30, 95447, Bayreuth, Germany.
Christian HilsMacromolecular Chemistry II, University of Bayreuth and Bavarian Polymer Institute, Keylab Synthesis and Molecular Characterization, Universitätsstrasse 30, 95447, Bayreuth, Germany.
Melina WeberMacromolecular Chemistry I, University of Bayreuth and Bavarian Polymer Institute, Universitätsstrasse 30, 95447, Bayreuth, Germany.
Klaus KregerMacromolecular Chemistry I, University of Bayreuth and Bavarian Polymer Institute, Universitätsstrasse 30, 95447, Bayreuth, Germany.ORCID http://orcid.org/0000-0003-3021-1311
Holger SchmalzMacromolecular Chemistry II, University of Bayreuth and Bavarian Polymer Institute, Keylab Synthesis and Molecular Characterization, Universitätsstrasse 30, 95447, Bayreuth, Germany.ORCID http://orcid.org/0000-0002-4876-0450
Hans-Werner SchmidtMacromolecular Chemistry I, University of Bayreuth and Bavarian Polymer Institute, Universitätsstrasse 30, 95447, Bayreuth, Germany.ORCID http://orcid.org/0000-0002-1761-1153
Bavarian Polymer Institute · DE

Funding

Deutsche Forschungsgemeinschaft SFB840 A2Deutsche Forschungsgemeinschaft SFB840 B8
6 · The paper itself

Abstract

Combining the unique corona structure of worm-like patchy micelles immobilized on a polymer fiber with the molecular self-assembly of 1,3,5-benzenetricarboxamides (BTAs) leads to hierarchical superstructures with a fir-tree-like morphology. For this purpose, worm-like patchy micelles bearing pendant, functional tertiary amino groups in one of the corona patches were prepared by crystallization-driven self-assembly and immobilized on a supporting polystyrene fiber by coaxial electrospinning. The obtained patchy fibers were then immersed in an aqueous solution of a tertiary amino-functionalized BTA to induce patch-mediated molecular self-assembly to well-defined fir-tree-like superstructures upon solvent evaporation. Interestingly, defined superstructures are obtained only if the pendant functional groups in the surface patches match with the peripheral substituents of the BTA, which is attributed to a local increase in BTA concentration at the polymer fibers' surface.

Indexed as

crystallization-driven self-assemblyhierarchical superstructuresmolecular self-assemblypatchy polymer fiberssupramolecular structures

Identifiers

PMID34038613
PMCPMC8518951
OpenAlexW3165423848

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.