ArticleAngewandte Chemie (International ed. in English)2021
Creation of High-Performance Heterogeneous Photocatalysts by Controlling Ligand Desorption and Particle Size of Gold Nanocluster.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 24 papers.
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Who cites it
24 citing papers in PubMed.
- Ligand Engineering of Dithiolate-Protected AuNano letters · 2026Article
- Drastic Enhancement of Activity and Durability for Oxygen Reduction Reaction by Melamine Modification for Platinum Nanocluster-Loaded Electrocatalysts.Small science · 2026Article
- Heterobinuclear Molecular Precursors Direct the Formation of Supported Subnanometer Cu-M Clusters with Tunable Catalytic Behavior.ACS applied materials & interfaces · 2025Article
- Recent Advances in Metal Nanoclusters: From Novel Synthesis to Emerging Applications.Molecules (Basel, Switzerland) · 2025Review
- Engineering Catalytic Efficiency by Thiolate-Protected Trimetallic (Cu, Pd, Au) Nanoclusters: Single-Atom Alloy Catalysts for Water-Gas Shift.ACS catalysis · 2025Article
- Disentangling the Effect of Key Parameters in Hydrogen Evolution for Rational Design of Metal-Semiconductor Photocatalysts via Self-Assembly.ACS applied materials & interfaces · 2025Article
- Ligand-Dependent Intracluster Interactions in Electrochemical COSmall (Weinheim an der Bergstrasse, Germany) · 2025Article
- Highly Selective Methanol Synthesis Using Electrochemical COSmall science · 2025Article
- Structural Evolution of Stapes Controls the Electrochemical COSmall (Weinheim an der Bergstrasse, Germany) · 2025Article
- Photosynthesis of AuNature communications · 2024Article
- Ultrafine Rhodium-Chromium Mixed-Oxide Cocatalyst with Facet-Selective Loading for Excellent Photocatalytic Water Splitting.Journal of the American Chemical Society · 2024Article
- Hydride-doped AgiScience · 2023Article
- Pyrolized Diatomaceous Biomass Doped with Epitaxially Growing Hybrid Ag/TiOMaterials (Basel, Switzerland) · 2023Article
- Programmable kernel structures of atomically precise metal nanoclusters for tailoring catalytic properties.Exploration (Beijing, China) · 2023Review
- Atomically Precise Metal Nanoclusters as Single Electron Transferers for Hydroborylation.Precision chemistry · 2023Article
- (AuAg)Precision chemistry · 2023Article
- Ligand engineering of AuChemical science · 2023Article
- Promoting Photocatalytic Carbon Dioxide Reduction by Tuning the Properties of Cocatalysts.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Review
- Effect of TiONanomaterials (Basel, Switzerland) · 2022Article
- CeOChemCatChem · 2022Article
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Authors and funding
17 authors.
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Abstract
Recently, the creation of new heterogeneous catalysts using the unique electronic/geometric structures of small metal nanoclusters (NCs) has received considerable attention. However, to achieve this, it is extremely important to establish methods to remove the ligands from ligand-protected metal NCs while preventing the aggregation of metal NCs. In this study, the ligand-desorption process during calcination was followed for metal-oxide-supported 2-phenylethanethiolate-protected gold (Au) 25-atom metal NCs using five experimental techniques. The results clearly demonstrate that the ligand-desorption process consists of ligand dissociation on the surface of the metal NCs, adsorption of the generated compounds on the support and desorption of the compounds from the support, and the temperatures at which these processes occurred were elucidated. Based on the obtained knowledge, we established a method to form a metal-oxide layer on the surface of Au NCs while preventing their aggregation, thereby succeeding in creating a water-splitting photocatalyst with high activity and stability.
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