ArticleNature communications2021
Living supramolecular polymerization of fluorinated cyclohexanes.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
What it found
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Who cites it
17 citing papers in PubMed, 73 citations in OpenAlex.
- Additive-induced kinetic control and chiral amplification in circularly polarized luminescence (CPL)-emitting secondary supramolecular polymers.Chemical science · 2026Article
- Noncovalent synthesis of higher-order super-heterostructures from structurally distinct molecular π-systems via secondary nucleation.Nature communications · 2026Article
- A Supramolecular Ferroelectric With Two Sublattices and Polarization Dependent Conductivity.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Kinetic Control and Trapping in the Supramolecular Polymerization of m-Terphenyl Bis-Urea Macrocycles.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- A coopetition-driven strategy of parallel/perpendicular aromatic stacking enabling metastable supramolecular polymerization.Nature communications · 2024Article
- Synthesis of Janus All-The Journal of organic chemistry · 2024Article
- Noncovalent synthesis of homo and hetero-architectures of supramolecular polymers via secondary nucleation.Nature communications · 2024Article
- Synthesis and supramolecular properties of all-Chemical communications (Cambridge, England) · 2024Article
- A library of vinyl phosphonate anions dimerize with cyanostars, form supramolecular polymers and undergo statistical sorting.Chemical science · 2023Article
- Molecular Engineering of the Kinetic Barrier in Seeded Supramolecular Polymerization.Journal of the American Chemical Society · 2023Article
- Spotting Local Environments in Self-Assembled Monolayer-Protected Gold Nanoparticles.ACS nano · 2022Article
- Molecular communications in complex systems of dynamic supramolecular polymers.Nature communications · 2022Article
- Adaptive Recombinant Nanoworms from Genetically Encodable Star Amphiphiles.Biomacromolecules · 2022Article
- Carbodiimide-Driven Dimerization and Self-Assembly of Artificial, Ribose-Based Amphiphiles.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Hierarchical self-assembly of aromatic peptide conjugates into supramolecular polymers: it takes two to tango.Chemical science · 2022Review
- Janus All-Cis 2,3,4,5,6-Pentafluorocyclohexyl Building Blocks Applied to Medicinal Chemistry and Bioactives Discovery Chemistry.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Supramolecular packing of alkyl substituted Janus face all-Chemical science · 2021Article
Corrections and comments
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Authors and funding
9 authors at 3 institutions in 3 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The development of powerful methods for living covalent polymerization has been a key driver of progress in organic materials science. While there have been remarkable reports on living supramolecular polymerization recently, the scope of monomers is still narrow and a simple solution to the problem is elusive. Here we report a minimalistic molecular platform for living supramolecular polymerization that is based on the unique structure of all-cis 1,2,3,4,5,6-hexafluorocyclohexane, the most polar aliphatic compound reported to date. We use this large dipole moment (6.2 Debye) not only to thermodynamically drive the self-assembly of supramolecular polymers, but also to generate kinetically trapped monomeric states. Upon addition of well-defined seeds, we observed that the dormant monomers engage in a kinetically controlled supramolecular polymerization. The obtained nanofibers have an unusual double helical structure and their length can be controlled by the ratio between seeds and monomers. The successful preparation of supramolecular block copolymers demonstrates the versatility of the approach.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.