ReviewChemistry (Weinheim an der Bergstrasse, Germany)2021
Phosphorus-Containing Superbases: Recent Progress in the Chemistry of Electron-Abundant Phosphines and Phosphazenes.
Review in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed, 55 citations in OpenAlex.
- Breaking the Ceiling of Boron-Boron Bonds: Understanding and Fine-Tuning Basicity in Diborane(4) Complexes.Journal of computational chemistry · 2026Article
- Recent advances in the synthesis and applications of cyanuric acid and its related analogues: a comprehensive review.RSC advances · 2026Review
- DFT Investigation into the Role of Superbases as the Auxiliary Groups in COMolecules (Basel, Switzerland) · 2026Article
- Design of 9H-fluoren-9-imine based organic superbases stabilized by proton-π interactions.Scientific reports · 2026Article
- Dual Lewis Acid-Base Molecular Cages Facilitate Cooperative NChemphyschem : a European journal of chemical physics and physical chemistry · 2025Article
- Secondary Phosphines Bearing N-Heterocyclic Imine Groups: Polarity Umpolung of Highly Electron-Rich P-H Bonds.Inorganic chemistry · 2025Article
- Phosphazenyl Phosphine Proton Sponges: Does the Proton-Chelating Effect Enhance Their Basicity?International journal of molecular sciences · 2025Article
- Strong Bases Design: Key Techniques and Stability Issues.International journal of molecular sciences · 2024Article
- A strategy for the controllable generation of organic superbases from benchtop-stable salts.Chemical science · 2024Article
- Molecular entanglement can strongly increase basicity.Communications chemistry · 2024Review
- Strong Bases and beyond: The Prominent Contribution of Neutral Push-Pull Organic Molecules towards Superbases in the Gas Phase.International journal of molecular sciences · 2024Review
- Oligonucleotide synthesis under mild deprotection conditions.New journal of chemistry = Nouveau journal de chimie · 2023Article
- Compact Rotaxane Superbases.Journal of the American Chemical Society · 2023Article
- Cyclo- and Polyphosphazenes for Biomedical Applications.Molecules (Basel, Switzerland) · 2022Review
- Highly Efficient Darzens Reactions Mediated by Phosphazene Bases under Mild Conditions.ChemistryOpen · 2022Article
- Modeling pInternational journal of molecular sciences · 2022Article
- From Stable PH-Ylides to α-Carbanionic Phosphines as Ligands for Zwitterionic Catalysts.Angewandte Chemie (International ed. in English) · 2022Article
- Phosphorus-Containing Superbases: Recent Progress in the Chemistry of Electron-Abundant Phosphines and Phosphazenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Review
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The renaissance of Brønsted superbases is primarily based on their pronounced capacity for a large variety of chemical transformations under mild reaction conditions. Four major set screws are available for the selective tuning of the basicity: the nature of the basic center (N, P, …), the degree of electron donation by substituents to the central atom, the possibility of charge delocalization, and the energy gain by hydrogen bonding. Within the past decades, a plethora of neutral electron-rich phosphine and phosphazene bases have appeared in the literature. Their outstanding properties and advantages over inorganic or charged bases have now made them indispensable as auxiliary bases in deprotonation processes. Herein, an update of the chemistry of basic phosphines and phosphazenes is given. In addition, due to widespread interest, their use in catalysis or as ligands in coordination chemistry is highlighted.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.