Evidence map›Paper›PMID 34014103›Full record

ArticleThe journal of physical chemistry letters2021

Free Carriers versus Self-Trapped Excitons at Different Facets of Ruddlesden-Popper Two-Dimensional Lead Halide Perovskite Single Crystals.

Mingli Liang, Weihua Lin, Qian Zhao, Xianshao Zou, Zhenyun Lan, Jie Meng, Qi Shi, Ivano E Castelli, Sophie E Canton, Tönu Pullerits and 1 more

Abstract read
In one paragraph

Article in The journal of physical chemistry letters, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Effects of Pressure on Exciton Absorption and Emission in Strongly Quantum-Confined CsPbBrThe journal of physical chemistry. C, Nanomaterials and interfaces · 2024
    Article
  6. Article
  7. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Mingli LiangDepartment of Chemistry, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark.ORCID https://orcid.org/0000-0002-1854-7026
Weihua LinChemical Physics and NanoLund, Lund University, Box 124, 22100 Lund, Sweden.
Qian ZhaoDepartment of Chemistry, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark.
Xianshao ZouChemical Physics and NanoLund, Lund University, Box 124, 22100 Lund, Sweden.
Zhenyun LanDepartment of Energy Conversion and Storage, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark.ORCID https://orcid.org/0000-0001-7943-5936
Jie MengDepartment of Chemistry, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark.ORCID https://orcid.org/0000-0002-3813-5221
Qi ShiChemical Physics and NanoLund, Lund University, Box 124, 22100 Lund, Sweden.
Ivano E CastelliDepartment of Energy Conversion and Storage, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark.ORCID https://orcid.org/0000-0001-5880-5045
Sophie E CantonEuropean XFEL, Holzkoppel 4, 22869 Schenefeld, Germany.ORCID https://orcid.org/0000-0003-4337-8129
Tönu PulleritsChemical Physics and NanoLund, Lund University, Box 124, 22100 Lund, Sweden.ORCID https://orcid.org/0000-0003-1428-5564
Kaibo ZhengDepartment of Chemistry, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark.ORCID https://orcid.org/0000-0002-7236-1070

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The physical origin of sub-band gap photoluminescence in Ruddlesden-Poppers two-dimensional (2D) lead halide perovskites (LHPs) is still under debate. In this paper, we studied the photoluminescence features from two different facets of 2D LHP single crystals: the in-plane facet (IF) containing the 2D inorganic layers and the facet perpendicular to the 2D layers (PF). At the IF, the free carriers (FCs) dominate due to the weak electron-phonon coupling in a symmetric lattice. At the PF, the strain accumulation along the 2D layers enhances the electron-phonon coupling and facilitates self-trapped exciton (STE) formation. The time-resolved PL studies indicate that free carriers (FCs) at the IF can move freely and display the trapping by the intrinsic defects. The STEs at the PF are not likely trapped by the defects due to the reduced mobility. However, with increasing STE density, the STE transport is promoted, enabling the trapping of STE by the intrinsic defects.

Identifiers

PMID34014103
PMCPMC8279734

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.