Evidence map›Paper›PMID 33986626›Full record

ArticleEuropean journal of inorganic chemistry2020

Tuning the copper(II)/copper(I) redox potential for more robust copper-catalyzed C-N bond forming reactions.

James D Cope, Henry U Valle, Ruby S Hall, Kathleen M Riley, Ekta Goel, Saborni Biswas, Michael P Hendrich, David O Wipf, Sean L Stokes, Joseph P Emerson

Open access · greenAbstract read
In one paragraph

Article in European journal of inorganic chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.

0numbers the graph read from it
0cells of the map it votes in
9citing papers in PubMed
1.5field-weighted citation impact, top 20% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

9 citing papers in PubMed, 29 citations in OpenAlex.

  1. Article
  2. Article
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  5. Aminoquinoline-Based Tridentate (Molecules (Basel, Switzerland) · 2024
    Article
  6. Cu-NHC Complex for Chan-Evans-Lam Cross-Coupling Reactions ofEuropean journal of organic chemistry · 2023
    Article
  7. Article
  8. Article
  9. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors at 2 institutions in 1 country.

James D CopeDepartment of Chemistry, Mississippi State University, Mississippi State, Mississippi, 39762, United States.
Henry U ValleDepartment of Chemistry, Mississippi State University, Mississippi State, Mississippi, 39762, United States.
Ruby S HallDepartment of Chemistry, Mississippi State University, Mississippi State, Mississippi, 39762, United States.
Kathleen M RileyDepartment of Chemistry, Mississippi State University, Mississippi State, Mississippi, 39762, United States.
Ekta GoelDepartment of Chemistry, Mississippi State University, Mississippi State, Mississippi, 39762, United States.
Saborni BiswasDepartment of Chemistry, Mississippi State University, Mississippi State, Mississippi, 39762, United States.
Michael P HendrichDepartment of Chemistry, Carnegie Mellon University, Pittsburg, PA 15213, United States.
David O WipfDepartment of Chemistry, Mississippi State University, Mississippi State, Mississippi, 39762, United States.
Sean L StokesDepartment of Chemistry, Mississippi State University, Mississippi State, Mississippi, 39762, United States.
Joseph P EmersonDepartment of Chemistry, Mississippi State University, Mississippi State, Mississippi, 39762, United States.
Mississippi State University · USCarnegie Mellon University · US

Funding

EPR and Mossbauer Characterization of Mn and Fe Proteins, Models, IntermediatesR01GM077387 · NIGMS · CARNEGIE-MELLON UNIVERSITY · PI HENDRICH, MICHAEL P · 2006 to 2019
$2.9M
NIGMS NIH HHS R01 GM077387
6 · The paper itself

Abstract

Complexes of copper and 1,10-phenanthroline have been utilized for organic transformations over the last 50 years. In many cases these systems are impacted by reaction conditions and perform best under an inert atmosphere. Here we explore the role the 1,10-phenanthroline ligand plays on the electronic structure and redox properties of copper coordination complexes, and what benefit related ligands may provide to enhance copper-based coupling reactions. Copper(II) triflate complexes bearing 1,10-phenanthroline (phen), ([Cu(phen)

Identifiers

PMID33986626
PMCPMC8115207
OpenAlexW3007839411

What OpenQuestion holds

Textmetadata
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.