ArticleNature communications2021
Oxidative cyclo-rearrangement of helicenes into chiral nanographenes.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
What it found
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Who cites it
19 citing papers in PubMed, 99 citations in OpenAlex.
- Exact benzannulation regulates packing and circularly polarized luminescence in a chiral bilayer nanographene.Chemical science · 2026Article
- Skeletal rearrangement of [4]helicenes under acidic conditions: dynamic chirality and improved properties by subsequent peripheral editing.Chemical science · 2026Article
- Continuous Photoflow Synthesis of Heterohelicenes.Organic letters · 2026Article
- On-surface synthesis of nonbenzenoid nanographenes through skeletal rearrangement reactions on Au(111).Science and technology of advanced materials · 2026Article
- Bilayer nanographenes: structure, properties, and synthetic challenges.Chemical Society reviews · 2025Review
- Halogen bond-modulated solid-state reordering and symmetry breaking of azahelicenes.Nature communications · 2025Article
- Quadruple[6]Helicene Featuring Pyrene Core: Unraveling Contorted Aromatic Core with Larger Effective Conjugation.Precision chemistry · 2024Article
- Theoretical Study on Vibrationally Resolved Electronic Spectra of Chiral Nanographenes.Molecules (Basel, Switzerland) · 2024Article
- Electroactive Carbazole-Based Polycyclic Aromatic Hydrocarbons: Synthesis, Photophysical Properties, and Computational Studies.ACS omega · 2024Article
- Facile fabrication of recyclable robust noncovalent porous crystals from low-symmetry helicene derivative.Nature communications · 2024Article
- Thia[Chemical science · 2024Article
- Synthesis and Structural and Optical Behavior of Dehydrohelicene-Containing Polycyclic Compounds.Molecules (Basel, Switzerland) · 2024Review
- Cyclotrimerization Approach to Symmetric [9]Helical Indenofluorenes: Diverting Cyclization Pathways.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Enantioselective synthesis of chiral quinohelicenes through sequential organocatalyzed Povarov reaction and oxidative aromatization.Nature communications · 2023Article
- Helical Bilayer Nanographenes: Impact of the Helicene Length on the Structural, Electrochemical, Photophysical, and Chiroptical Properties.Journal of the American Chemical Society · 2023Article
- Helicity-modulated remote C-H functionalization.Science advances · 2023Article
- BINOL-like atropisomeric chiral nanographene.Chemical science · 2023Article
- Diels-Alder Cycloaddition with CO, COMaterials (Basel, Switzerland) · 2021Review
- Scholl reaction as a powerful tool for the synthesis of nanographenes: a systematic review.RSC advances · 2021Review
Corrections and comments
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Authors and funding
7 authors at 2 institutions in 2 countries.
Funding
Abstract
Nanographenes are emerging as a distinctive class of functional materials for electronic and optical devices. It is of remarkable significance to enrich the precise synthetic chemistry for these molecules. Herein, we develop a facile strategy to recompose helicenes into chiral nanographenes through a unique oxidative cyclo-rearrangement reaction. Helicenes with 7~9 ortho-fused aromatic rings are firstly oxidized and cyclized, and subsequently rearranged into nanographenes with an unsymmetrical helicoid shape through sequential 1,2-migrations. Such skeletal reconstruction is virtually driven by the gradual release of the strain of the highly distorted helicene skeleton. Importantly, the chirality of the helicene precursor can be integrally inherited by the resulting nanographene. Thus, a series of chiral nanographenes are prepared from a variety of carbohelicenes and heterohelicenes. Moreover, such cyclo-rearrangement reaction can be sequentially or simultaneously associated with conventional oxidative cyclization reactions to ulteriorly enrich the geometry diversity of nanographenes, aiming at innovative properties.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.