Evidence map›Paper›PMID 33978974›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021

Structure and Reactivity of N-Heterocyclic Alkynyl Hypervalent Iodine Reagents.

Eliott Le Du, Thibaut Duhail, Matthew D Wodrich, Rosario Scopelliti, Farzaneh Fadaei-Tirani, Elsa Anselmi, Emmanuel Magnier, Jerome Waser

Open access · hybridAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
1.7field-weighted citation impact, top 17% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed, 19 citations in OpenAlex.

  1. Review
  2. Article
  3. Recent progress in alkynylation with hypervalent iodine reagents.Chemical communications (Cambridge, England) · 2023
    Review
  4. Review
  5. Structure and Reactivity of N-Heterocyclic Alkynyl Hypervalent Iodine Reagents.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 3 institutions in 2 countries.

Eliott Le DuLaboratory of Catalysis and Organic Synthesis, Ecole Polytechnique Fédérale de Lausanne, EPFL SB ISIC LCSO, BCH 4306, 1015, Lausanne, Switzerland.
Thibaut DuhailInstitut Lavoisier de Versailles, Université Paris-Saclay, UVSQ, CNRS, UMR 8180, 7800, Versailles, France.
Matthew D WodrichLaboratory of Catalysis and Organic Synthesis, Ecole Polytechnique Fédérale de Lausanne, EPFL SB ISIC LCSO, BCH 4306, 1015, Lausanne, Switzerland.
Rosario ScopellitiInstitute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne, EPFL SB ISIC GE, BCH 2111, 1015 Lausanne, EPFL SB ISIC LCSO, BCH 4306, 1015, Lausanne, Switzerland.
Farzaneh Fadaei-TiraniInstitute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne, EPFL SB ISIC GE, BCH 2111, 1015 Lausanne, EPFL SB ISIC LCSO, BCH 4306, 1015, Lausanne, Switzerland.
Elsa AnselmiInstitut Lavoisier de Versailles, Université Paris-Saclay, UVSQ, CNRS, UMR 8180, 7800, Versailles, France.
Emmanuel MagnierInstitut Lavoisier de Versailles, Université Paris-Saclay, UVSQ, CNRS, UMR 8180, 7800, Versailles, France.
Jerome WaserLaboratory of Catalysis and Organic Synthesis, Ecole Polytechnique Fédérale de Lausanne, EPFL SB ISIC LCSO, BCH 4306, 1015, Lausanne, Switzerland.ORCID http://orcid.org/0000-0002-4570-914X
École Polytechnique Fédérale de Lausanne · CHCentre National de la Recherche Scientifique · FRUniversité de Tours · FR

Funding

Agence Nationale de la Recherche ANR-17-CE07-0048-01Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung 200020_182798
6 · The paper itself

Abstract

Ethynylbenziodoxol(on)e (EBX) cyclic hypervalent iodine reagents have become popular reagents for the alkynylation of radicals and nucleophiles, but only offer limited possibilities for further structure and reactivity fine-tuning. Herein, the synthesis of new N-heterocyclic hypervalent iodine reagents with increased structural flexibility based on amide, amidine and sulfoximine scaffolds is reported. Solid-state structures of the reagents are reported and the analysis of the I-C

Indexed as

alkynyl transferdensity functional calculationsheterocycleshypervalent iodinesulfoximine

Identifiers

PMID33978974
PMCPMC8361724
OpenAlexW3162202674

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.