ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021
Slow Magnetic Relaxation in Mono- and Bimetallic Lanthanide Tetraimido-Sulfate S(NtBu)
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Magnetic, EPR, and Computational Insights into ∼D6h Tb(III) and Gd(III) Complexes.Inorganic chemistry · 2026Article
- Charge Density and Magnetic Properties in Cobalt(II) Single-Molecule Magnets: Impact of Ligand Substitution.Chemphyschem : a European journal of chemical physics and physical chemistry · 2026Article
- Slow Magnetic Relaxation in Mono- and Bimetallic Lanthanide Tetraimido-Sulfate S(NtBu)Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
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Authors and funding
5 authors.
Funding
Abstract
Lanthanide ions are particularly well-suited for the design of single-molecule magnets owing to their large unquenched orbital angular momentum and strong spin-orbit coupling that gives rise to high magnetic anisotropy. Such nanoscopic bar magnets can potentially revolutionize high-density information storage and processing technologies, if blocking temperatures can be increased substantially. Exploring non-classical ligand scaffolds with the aim to boost the barriers to spin-relaxation are prerequisite. Here, the synthesis, crystallographic and magnetic characterization of a series of each isomorphous mono- and dinuclear lanthanide (Ln=Gd, Tb, Dy, Ho, Er) complexes comprising tetraimido sulfate ligands are presented. The dinuclear Dy complex [{(thf)
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