Evidence map›Paper›PMID 33973463›Full record

ArticleJournal of the American Chemical Society2021

Direct Transition from Triplet Excitons to Hybrid Light-Matter States via Triplet-Triplet Annihilation.

Chen Ye, Suman Mallick, Manuel Hertzog, Markus Kowalewski, Karl Börjesson

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.

0numbers the graph read from it
0cells of the map it votes in
16citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

16 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
  4. Article
  5. Article
  6. Article
  7. Article
  8. Article
  9. Review
  10. Review
  11. Article
  12. Triplet-triplet Annihilation Dynamics of Naphthalene.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022
    Article
  13. Interplay between Polaritonic and Molecular Trap States.The journal of physical chemistry. C, Nanomaterials and interfaces · 2022
    Article
  14. Article
  15. Review
  16. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Chen YeDepartment of Chemistry and Molecular Biology, University of Gothenburg, Kemigården 4, 412 96 Gothenburg, Sweden.
Suman MallickDepartment of Chemistry and Molecular Biology, University of Gothenburg, Kemigården 4, 412 96 Gothenburg, Sweden.
Manuel HertzogDepartment of Chemistry and Molecular Biology, University of Gothenburg, Kemigården 4, 412 96 Gothenburg, Sweden.
Markus KowalewskiDepartment of Physics, Stockholm University, Albanova University Centre, 106 91 Stockholm, Sweden.
Karl BörjessonDepartment of Chemistry and Molecular Biology, University of Gothenburg, Kemigården 4, 412 96 Gothenburg, Sweden.ORCID http://orcid.org/0000-0001-8533-201X

Funding

European Research Council 852286
6 · The paper itself

Abstract

Strong light-matter coupling generates hybrid states that inherit properties of both light and matter, effectively allowing the modification of the molecular potential energy landscape. This phenomenon opens up a plethora of options for manipulating the properties of molecules, with a broad range of applications in photochemistry and photophysics. In this article, we use strong light-matter coupling to transform an endothermic triplet-triplet annihilation process into an exothermic one. The resulting gradual on-off photon upconversion experiment demonstrates a direct conversion between molecular states and hybrid light-matter states. Our study provides a direct evidence that energy can relax from nonresonant low energy molecular states directly into hybrid light-matter states and lays the groundwork for tunable photon upconversion systems that modify molecular properties in situ by optical cavities rather than with chemical modifications.

Identifiers

PMID33973463
PMCPMC8154526

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.