ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021
Phosphetes via Transition Metal Free Ring Closure - Taking the Proper Turn at a Thermodynamic Crossing.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
5 citing papers in PubMed, 20 citations in OpenAlex.
- Stereodynamism in Chiral Polyaromatic Phosphepines.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Carborane-Decorated Siloles with Highly Efficient Solid-State Emissions - What Drives the Photophysical Properties?Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Cobalt- or rhodium-catalyzed synthesis of 1,2-dihydrophosphete oxidesChemical science · 2024Article
- Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes.Molecules (Basel, Switzerland) · 2022Article
- Phosphetes via Transition Metal Free Ring Closure - Taking the Proper Turn at a Thermodynamic Crossing.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
5 authors at 2 institutions in 2 countries.
Funding
Abstract
A transition metal free route to phosphetes featuring an exocyclic alkene unit is presented. In this approach phosphanides are added to a variety of diynes generating phosphaallylic intermediates which depending on the reaction conditions transform either to phosphetes or the corresponding phospholes. Investigation of the reaction mechanism by combined quantum chemical and experimental means identifies phosphole formation as thermodynamically controlled reaction path, whereas kinetic control furnishes the corresponding phosphetes. Structural and luminescence properties of the rare class of phosphetes are explored, as well as for selected key intermediates.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.