Evidence map›Paper›PMID 33968463›Full record

ArticleACS catalysis2021

Z-Selective Dienylation Enables Stereodivergent Construction of Dienes and Unravels a Ligand-Driven Mechanistic Dichotomy.

Hang T Dang, Viet D Nguyen, Graham C Haug, Ngan T H Vuong, Hadi D Arman, Oleg V Larionov

Abstract read
In one paragraph

Article in ACS catalysis, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
  4. Review
  5. Article
  6. Article
  7. Article
  8. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Hang T DangDepartment of Chemistry, The University of Texas at San Antonio, San Antonio, Texas 78249, United States.
Viet D NguyenDepartment of Chemistry, The University of Texas at San Antonio, San Antonio, Texas 78249, United States.
Graham C HaugDepartment of Chemistry, The University of Texas at San Antonio, San Antonio, Texas 78249, United States.
Ngan T H VuongDepartment of Chemistry, The University of Texas at San Antonio, San Antonio, Texas 78249, United States.
Hadi D ArmanDepartment of Chemistry, The University of Texas at San Antonio, San Antonio, Texas 78249, United States.
Oleg V LarionovDepartment of Chemistry, The University of Texas at San Antonio, San Antonio, Texas 78249, United States.

Funding

New organosulfur-based strategies for efficient and selective organic synthesis.R01GM134371 · NIGMS · UNIVERSITY OF TEXAS SAN ANTONIO · PI LARIONOV, OLEG V · 2019 to 2022
$1.1M
NIGMS NIH HHS R01 GM134371
6 · The paper itself

Abstract

Development of stereoselective and efficient reactions for construction of conjugated dienes and polyenes has remained at the forefront of organic chemistry, due to their key roles in medicinal chemistry, organic synthesis, and materials science. The synthesis of conjugated dienes and polyenes is typically accomplished in a multistep manner by sequential installation of individual C=C bonds because it allows for control of stereoselectivity and efficiency of formation of each double bond. A conceptually distinct dienylation approach entails a stereoselective appendage of a four-carbon unit, shortcutting diene synthesis. Dienylation with sulfolene provided a direct route to

Indexed as

conjugated dienescross-couplingdiastereoselectivitypalladiumphosphine

Identifiers

PMID33968463
PMCPMC8098720

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.