Evidence map›Paper›PMID 33949852›Full record

ArticleJournal of the American Chemical Society2021

Electrophotocatalytic Acetoxyhydroxylation of Aryl Olefins.

He Huang, Tristan H Lambert

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.

0numbers the graph read from it
0cells of the map it votes in
20citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

20 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
  4. Article
  5. Article
  6. Article
  7. Article
  8. Photoelectrochemical oxidative C(spNature communications · 2023
    Article
  9. Article
  10. Review
  11. Article
  12. Redox catalysisChemical science · 2023
    Review
  13. Article
  14. Olefin Dihydroxylation Using Nitroarenes as Photoresponsive Oxidants.Angewandte Chemie (International ed. in English) · 2023
    Article
  15. Review
  16. Regiodivergent Electrophotocatalytic Aminooxygenation of Aryl Olefins.Journal of the American Chemical Society · 2022
    Article
  17. Article
  18. Catalytic Synthesis of Cyclopropenium Cations with Rh-Carbynoids.Journal of the American Chemical Society · 2022
    Article
  19. Review
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors.

He HuangDepartment of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853, United States.
Tristan H LambertDepartment of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853, United States.ORCID 0000-0002-7720-3290

Funding

CATALYTIC PLATFORMS USING AROMATIC IONS AND OTHER CHARGED SPECIESR35GM127135 · NIGMS · CORNELL UNIVERSITY · PI Tristan H Lambert · 2018 to 2026
$4.4M
NIGMS NIH HHS R35 GM127135
6 · The paper itself

Abstract

A method for the acetoxyhydroxylation of olefins with syn stereoselectivity under electrophotocatalytic conditions is described. The procedure uses a trisaminocyclopropenium (TAC) ion catalyst with visible light irradiation under a controlled electrochemical potential to convert aryl olefins to the corresponding glycol monoesters with high chemo- and diastereoselectivity. This reaction can be performed in batch or in flow, enabling multigram synthesis of the monoester products.

Indexed as

AlkenesCatalysisCyclopropanesEstersHydroxylationMolecular StructureStereoisomerismAlkenesCyclopropanesEsters

Identifiers

PMID33949852
PMCPMC8145777

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.