Evidence map›Paper›PMID 33949521›Full record

ArticleChemical Society reviews2021

A reaction-coordinate perspective of magnetic relaxation.

Cassidy E Jackson, Ian P Moseley, Roxanna Martinez, Siyoung Sung, Joseph M Zadrozny

Abstract read
In one paragraph

Article in Chemical Society reviews, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.

0numbers the graph read from it
0cells of the map it votes in
23citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

23 citing papers in PubMed.

  1. Article
  2. Article
  3. Amplified electron-spin thermal sensitivity in Mn(II) complexes.Dalton transactions (Cambridge, England : 2003) · 2026
    Article
  4. Article
  5. Article
  6. Review
  7. Article
  8. Investigating LiRSC advances · 2025
    Article
  9. A Spectrochemical Series for Electron Spin Relaxation.Journal of the American Chemical Society · 2025
    Article
  10. Review
  11. Article
  12. Article
  13. Article
  14. Quantum Mimicry With Inorganic Chemistry.Comments on modern chemistry. Part A, Comments on inorganic chemistry : a journal of critical discussion of the current literature · 2024
    Article
  15. Article
  16. Dynamic Magnetic Properties of Germole-ligated Lanthanide Sandwich Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023
    Article
  17. Article
  18. Article
  19. Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Cassidy E JacksonDepartment of Chemistry, Colorado State University, Fort Collins, CO, USA. joe.zadrozny@colostate.edu.
Ian P MoseleyDepartment of Chemistry, Colorado State University, Fort Collins, CO, USA. joe.zadrozny@colostate.edu.ORCID http://orcid.org/0000-0003-1392-0220
Roxanna MartinezDepartment of Chemistry, Colorado State University, Fort Collins, CO, USA. joe.zadrozny@colostate.edu.
Siyoung SungDepartment of Chemistry, Colorado State University, Fort Collins, CO, USA. joe.zadrozny@colostate.edu.
Joseph M ZadroznyDepartment of Chemistry, Colorado State University, Fort Collins, CO, USA. joe.zadrozny@colostate.edu.ORCID http://orcid.org/0000-0002-1309-6545

Funding

A Coordination Chemistry Approach to High-Field EPR ImagingR21EB027293 · NIBIB · COLORADO STATE UNIVERSITY · PI ZADROZNY, JOSEPH M · 2018 to 2020
$534k
NIBIB NIH HHS R21 EB027293
6 · The paper itself

Abstract

Understanding and utilizing the dynamic quantum properties of metal ions is the frontier of many next generation technologies. One property in particular, magnetic relaxation, is a complicated physical phenomenon that is scarcely treated in undergraduate coursework. Consequently, principles of magnetic relaxation are nearly impenetrable to starting synthetic chemists, who ultimately design the molecules that fuel new discoveries. In this Tutorial Review, we describe a new paradigm for thinking of magnetic relaxation in metal complexes in terms of a simple reaction-coordinate diagram to facilitate access to the field. We cover the main mechanisms of both spin-lattice (T1) and spin-spin (T2) relaxation times within this conceptual framework and how molecular and environmental design affects these times. Ultimately, we show that many of the scientific methods used by inorganic chemists to study and manipulate reactivity are also useful for understanding and controlling magnetic relaxation. We also describe the cutting edge of magnetic relaxation within this paradigm.

Identifiers

PMID33949521
PMCPMC8215782

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.