ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021
Steric Effects on the Thermal Processes of Hemithioindigo Based Molecular Motor Rotation.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- A supercharged molecular motor operating by constitutional alteration and proton transfer.Nature chemistry · 2026Article
- Photoisomerizing molecules in biological membranes.Nature reviews. Chemistry · 2026Review
- Directionality Reversal and Shift of Rotational Axis in a Hemithioindigo Macrocyclic Molecular Motor.Journal of the American Chemical Society · 2024Article
- Sterically driven current reversal in a molecular motor model.Proceedings of the National Academy of Sciences of the United States of America · 2023Article
- Nanoporous Films with Oriented Arrays of Molecular Motors for Photoswitching the Guest Adsorption and Diffusion.Angewandte Chemie (International ed. in English) · 2023Article
- Through the Eyes of Creators: Observing Artificial Molecular Motors.ACS nanoscience Au · 2022Review
- Active Mechanical Threading by a Molecular Motor.Angewandte Chemie (International ed. in English) · 2022Article
- Designing light-driven rotary molecular motors.Chemical science · 2021Review
- Steric Effects on the Thermal Processes of Hemithioindigo Based Molecular Motor Rotation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
Tuning the thermal behavior of light driven molecular motors is fundamentally important for their future rational design. In many molecular motors thermal ratcheting steps are comprised of helicity inversions, energetically stabilizing the initial photoproducts. In this work we investigated a series of five hemithioindigo (HTI) based molecular motors to reveal the influence of steric hindrance in close proximity to the rotation axle on this process. Applying a high yielding synthetic procedure, we synthesized constitutional isomeric derivatives to distinguish between substitution effects at the aromatic and aliphatic position on the rotor fragment. The kinetics of thermal helix inversions were elucidated using low temperature
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